|  | Lunn, George / Sansone, Eric B.
Destruction of Hazardous Chemicals in the Laboratory
 3. Auflage Mai 2012
109,- Euro
2012. 800 Seiten, Hardcover
- Praktikerbuch -
ISBN 978-0-470-48755-6 - John Wiley & Sons
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| Kurzbeschreibung
When it is time to dispose of hazardous materials they cannot just be thrown out. This subject has become of increasing importance with recent reports of the detection of pharmaceuticals in the water supply Destruction of Hazardous Chemicals in the Laboratory follows the same general approach as the first and second editions, but includes a number of new chapters, such as one on using advanced oxidation techniques as a general means of degrading chemicals. Encouraging prudent waste destruction for a cleaner environment, this book offers a clear roadmap to correct practices.
Aus dem Inhalt
PREFACE xi
ACKNOWLEDGMENTS xiii
INTRODUCTION 1
SPECIFIC METHODS FOR THE DESTRUCTION OF HAZARDOUS CHEMICALS IN THE LABORATORY 17
Acetonitrile 19
Acid Halides and Anhydrides 23
Aflatoxins 29
Alkali and Alkaline Earth Metals 37
Alkali Metal Alkoxides 41
Anatoxin-A 43
Aromatic Amines 47
Arsenic 57
Azides 61
Azo and Azoxy Compounds and Tetrazenes 69
Boron Trifluoride and Inorganic Fluorides 77
Botulinum Toxins 81
Brevetoxins 85
Butyllithium 89
Calcium Carbide 93
Carbamic Acid Esters 95
Carbofuran 99
Chloromethylsilanes and Silicon Tetrachloride 101
N-Chlorosuccinimide and Chloramine-T 103
Chlorosulfonic Acid 105
Chromium(VI) 107
Citrinin 113
Complex Metal Hydrides 121
Cyanides and Cyanogen Bromide 129
Cylindrospermopsin 137
Diisopropyl Fluorophosphate 141
Dimethyl Sulfate and Related Compounds 151
Dyes and Biological Stains 163
Ethidium Bromide 201
Haloethers 211
Halogenated Compounds 217
Halogens 229
Heavy Metals 233
Hexamethylphosphoramide 241
Hydrazines 245
Hypochlorites 257
Mercury 261
2-Methylaziridine 267
1-Methyl-4-phenyl-1,2,3,6-tetrahydropyridine (MPTP) 271
Microcystins 277
4-Nitrobiphenyl 283
3-Nitrofluoranthene and 3-Aminofluoranthene 287
Nitrogen Tetroxide 291
N-Nitroso Compounds: Nitrosamides 293
N-Nitroso Compounds: Nitrosamines 307
Ochratoxin A 319
Organic Nitriles 327
Osmium Tetroxide 331
Palytoxin 335
Patulin 339
Peracids 347
Perchlorates 349
Peroxides and Hydroperoxides 355
Phenol 359
Phosgene 363
Phosphorus and Phosphorus Pentoxide 367
Picric Acid 371
Polycyclic Aromatic Hydrocarbons 375
Polycyclic Heterocyclic Hydrocarbons 387
Potassium Permanganate 405
b-Propiolactone 407
Protease Inhibitors 411
Ricin 417
Saxitoxin 421
Selenium Compounds 425
Sodium Amide 427
Sterigmatocystin 429
Sulfonyl Fluoride Enzyme Inhibitors 437
Sulfur-Containing Compounds 443
T-2 Toxin 449
Tetrodotoxin 455
Triacetone Triperoxide 459
Uranyl Compounds 463
METHODS FOR THE DESTRUCTION OF PHARMACEUTICALS IN THE LABORATORY 467
Pharmaceuticals: General Considerations 469
A: Potassium Permanganate 549
B: Sodium Hypochlorite 567
C: Nickel-Aluminum Alloy Reduction 575
D: Fenton's Reagent 583
E: Photo-Fenton Reaction 587
F: Hydrogen Peroxide 591
G: Hydrogen Peroxide and Horseradish Peroxidase 593
H: Ozone 595
I: Hydroxylamine Degradation of b-Lactams 603
J: Miscellaneous Chemical Degradation Procedures 605
K: Photolytic Degradation Procedures 613
L: Decontamination of Aqueous Solutions 627
NONSPECIFIC METHODS FOR THE DESTRUCTION OF HAZARDOUS CHEMICALS IN THE LABORATORY 631
APPENDIXES 655
APPENDIX I: Procedures for Drying Organic Solvents 657
APPENDIX II: Safety Considerations with Potassium Permanganate 661
MOLECULAR FORMULA INDEX 671
CAS REGISTRY NUMBER INDEX 681
CROSS INDEX OF PHARMACEUTICAL NAMES 693
CROSS-INDEX OF NAMES FOR DYES AND BIOLOGICAL STAINS 729
NAME INDEX 757
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