|  | Chatgilialoglu, Chryssostomos / Studer, Armido
Encyclopedia of Radicals in Chemistry, Biology and Materials
 1. Auflage Februar 2012
850,- Euro
2012. 2324 Seiten, 4 Bände, Hardcover
- Handbuch/Nachschlagewerk -
ISBN 978-0-470-97125-3 - John Wiley & Sons
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| Kurzbeschreibung
In recent years, free radicals have played an important role in various disciplines, ranging from organic synthesis to biology and medicine, polymer chemistry and materials science. The aim of this handbook is to offer for the first time a description of free radicals within an interdisciplinary and multidisciplinary context, connecting structural characteristics and chemical properties to their applications in different areas of chemistry and related disciplines.
The Handbook covers not only basic concepts and chemical synthesis, but also touches on various aspects concerning the role of free radicals in materials and life sciences. The reader will find a balanced contribution of topics related to free radicals covering for example, their role in proteomics, genomics and lipidomics as well as their enormous potential in synthesis and technology.
The Handbook will be interesting for anybody working in the field of free radicals in the broadest sense. It will address scientists who want to enter the interdisciplinary field of free radicals. In particular, it is aimed primarily at chemists and life science researchers who want to gain a wider and deeper understanding of free radicals which will allow them to apply free radicals in their own scientific field.
Aus dem Inhalt
VOLUME 1: BASIC CONCEPTS AND METHODOLOGIES
Preface ix
List of Contributors xi
Abbreviations and Acronymns xix
1 The History of Free Radical Chemistry 1
Thomas T. Tidwell
2 Overview of Radical Initiation 37
Jacques Lalevée and Jean Pierre Fouassier
3 Basic Concepts on Radical Chain Reactions 57
Michael S. Sherburn
4 Thermochemistry and Hydrogen Transfer Kinetics 81
Andreas A. Zavitsas
5 Radical Kinetics and Clocks 107
Martin Newcomb
6 Radical Rearrangements: Ester-Substituted Radicals and Hydrogen Atom Migrations 125
Kaname Sasaki, Ian Cumpstey and David Crich
7 Analysis of Radicals by EPR 147
John C. Walton
8 Structures and Reactivity of Radicals Followed by Magnetic Resonance 175
Alexandra Yurkovskaya, Olga Morozova and Georg Gescheidt
9 Matrix Isolation of Radicals 207
Artur Mardyukov and Wolfram Sander
10 Supramolecular Radical Chemistry 229
Marco Lucarini
11 Redox Properties of Radicals 249
David C. Magri and Mark S. Workentin
12 Photo Induced Radical Reactions 275
Julia P´erez-Prieto and Miguel A. Miranda
13 Radical Cation/Anion and Neutral Radicals: A Comparison 301
Amber N. Hancock and J. M. Tanko
14 The SRN1 Reaction 333
Javier I. Bardagí, Victoria A. Vaillard and Roberto A. Rossi
15 Photoinduced Reactions of Radical Ions via Charge Separation 365
Shunichi Fukuzumi and Kei Ohkubo
16 Radiation-Induced Radical Reactions 395
Krzysztof Bobrowski
17 Free Radical Chemistry in Room-Temperature Ionic Liquids 433
Ilya A. Shkrob and James F. Wishart
18 Radical Stability--Thermochemical Aspects 449
Johnny Hioe and Hendrik Zipse
19 Radical Chemistry in the Gas Phase 477
Christian Alcaraz, Ingo Fischer and Detlef Schröder
20 Atmospheric Radical Chemistry 503
Paul H. Wine and J. Michael Nicovich
VOLUME 2: SYNTHETIC STRATEGIES AND APPLICATIONS
21 Tin Hydrides and Functional Group Transformations 529
Hannelore Jasch and Markus R. Heinrich
22 Silanes as Reducing Reagents in Radical Chemistry 561
Chryssostomos Chatgilialoglu and Vitaliy I. Timokhin
23 Boron in Radical Chemistry 601
Philippe Renaud
24 Intramolecular Homolytic Substitutions in Synthesis 629
Sara H. Kyne and Carl H. Schiesser
25 Stereoselective Radical Reactions 655
Yong-Hua Yang and Mukund P. Sibi
26 Unusual Cyclizations 693
Kerry Gilmore and Igor V. Alabugin
27 Radical Cascade Reactions 729
Alexandre Baralle, Abdulkader Baroudi, Marion Daniel, Louis Fensterbank, Jean-Philippe Goddard, Emmanuel Lacôte, Marie-Hélène Larraufie, Giovanni Maestri, Max Malacria and Cyril Ollivier
28 Main-Group Elements in Radical Chemistry 767
Alexandre Baralle, Abdulkader Baroudi, Marion Daniel, Louis Fensterbank, Jean-Philippe Goddard, Emmanuel Lacôte, Marie-Hélène Larraufie, Giovanni Maestri, Max Malacria and Cyril Ollivier
29 Organic Electron Donors 817
John A. Murphy
30 Organic Synthesis Using Samarium Diiodide 849
Susannah C. Coote, Robert A. Flowers II, Troels Skrydstrup and David J. Procter
31 Manganese(III) Acetate, CAN, and Fe(III) Salts in Oxidative Radical Chemistry 901
Jonathan W. Burton
32 Halogen and Chalcogen Transfer Chemistry 943
Chaozhong Li
33 Xanthates and Related Derivatives as Radical Precursors 965
Samir Z. Zard
34 Epoxides in Titanocene-Mediated and -Catalyzed Radical Reactions 989
Andreas Gansäuer and André Fleckhaus
35 Transition Metals and Radicals 1003
Hideki Yorimitsu
36 Unusual Radical Acceptors 1019
Piero Spagnolo and Daniele Nanni
37 Radical Arylations 1059
Santiago E. Vaillard and Armido Studer
38 Nitroxides in Synthetic Radical Chemistry 1095
Chittreeya Tansakul and Rebecca Braslau
39 Radicals and Carbohydrates 1131
Inés Pérez-Martín and Ernesto Suárez
40 Electrochemically Initiated Radical Reactions 1175
Martin A. Bohn, Anna Paul and Gerhard Hilt
41 Synthetic Radical Photochemistry 1217
Emmanuel Riguet and Norbert Hoffmann
42 Radical Chemistry by Using Flow Microreactor Technology 1243
Takahide Fukuyama and Ilhyong Ryu
VOLUME 3: CHEMICAL BIOLOGY
43 Biological Chemistry of Reactive Oxygen Species 1259
Christine C. Winterbourn
44 Reactions of Small Reactive Species with DNA 1283
Nicholas E. Geacintov and Vladimir Shafirovich
45 Oxidatively Generated Nucleobase Modifications in Isolated and Cellular DNA 1319
Jean Cadet, Thierry Douki, Didier Gasparutto, Jean-Luc Ravanat and J. Richard Wagner
46 Oxidatively Formed Sugar Radicals in Nucleic Acids 1345
Thanasis Gimisis and Chryssostomos Chatgilialoglu
47 Understanding DNA Radicals Employing Theory and Electron Spin Resonance Spectroscopy 1371
Amitava Adhikary, Anil Kumar, David Becker and Michael D. Sevilla
48 Charge Transfer in DNA 1397
Mamoru Fujitsuka and Tetsuro Majima
49 Oxidative Damage to Proteins 1425
Michael J. Davies
50 Radical-Based Damage of Sulfur-Containing Amino Acid Residues 1459
Christian Schöneich
51 Electron Transfer in Peptides and Proteins 1475
Bernd Giese, Sonja Eckhardt and Miriam Lauz
52 Radical Enzymes 1501
Wolfgang Buckel and Bernard T. Golding
53 Theoretical Studies of Radical Enzymes 1547
Gregory M. Sandala, David M. Smith and Leo Radom
54 Lipid Peroxidation 1577
Etsuo Niki
55 Lipid Isomerization 1599
Carla Ferreri and Chryssostomos Chatgilialoglu
56 Antioxidants in Chemistry and Biology 1623
Luca Valgimigli and Derek A. Pratt
57 Free Radicals and Metabolic Disorders 1679
Guy Cohen, Yael Riahi and Shlomo Sasson
VOLUME 4: POLYMERS AND MATERIALS
58 Radical Polymerization in Industry 1701
Peter Nesvadba
59 Kinetics of Polymerizations 1737
Michael Buback and Gregory T. Russell
60 Fundamentals of Controlled/Living Radical Polymerization 1785
Krzysztof Matyjaszewski
61 Nitroxide-Mediated Polymerization and its Applications 1813
Didier Gigmes and Sylvain R. A. Marque
62 Atom Transfer Radical Polymerization (ATRP) and Addition (ATRA) and Applications 1851
Tomislav Pintauer and Krzysztof Matyjaszewski
63 Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization: Mechanism, Process and Applications 1895
Christopher Barner-Kowollik, James P. Blinco, Mathias Destarac, Kristofer J. Thurecht and S´ebastien Perrier
64 Sb, Bi, Te, and I-Transfer Polymerization and Applications 1931
Shigeru Yamago and Eiichi Kayahara
65 Spin Labels and Spin Probes 1965
David Bardelang, Mica¨el Hardy, Olivier Ouari and Paul Tordo
66 Radical Thiol-X Click Chemistry 2017
Niels ten Brummelhuis and Helmut Schlaad
67 Conducting Polymers: Applications in Electronics and Photovoltaics 2057
Huanli Dong and Wenping Hu
68 Silicon Radical Surface Chemistry 2081
Bart Rijksen, Mabel A. Caipa Campos, Jos M. J. Paulusse and Han Zuilhof
69 Persistent and Stable Silyl Radicals 2117
Boris Tumanskii, Miriam Karni and Yitzhak Apeloig
70 Physical Properties of Thiazyl Radicals Toward Conductive and Magnetic Materials 2147
Kunio Awaga
71 Polyradicals in Batteries 2163
Kenichi Oyaizu and Hiroyuki Nishide
72 Radical Chemistry on Fullerenes 2171
Manolis D. Tzirakis and Michael Orfanopoulos
73 A Paradigm for the Radical-Mediated Photochemical Synthesis of Metal Nanostructures 2197
Juan C. Scaiano, Kevin G. Stamplecoskie, Katherine L. McGilvray and Natalia L. Pacioni
Author Index 2211
Subject Index
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