|  | Bakhmutov, Vladimir I.
Dihydrogen Bond
Principles, Experiments, and Applications
 1. Auflage - April 2008
125,- Euro
2008. 242 Seiten, Hardcover
ISBN-10: 0-470-18096-X
ISBN-13: 978-0-470-18096-9 - John Wiley & Sons
Preis inkl. Mehrwertsteuer zzgl. Versandkosten.
Probekapitel
Kurzbeschreibung
The first book to describe the phenomenon of dihydrogen bonding in the solid-state, the gas phase, and in solution while considering numerous theoretical and experimental methodologies for its determination and characterization. The book considers the nature of dihydrogen bonds in the context of theoretical and experimental data surrounding their formation, classifying these bonds as a function of energy, geometry, strength of proton-donor and proton-acceptor sites, and establishing correlations between energetic and geometrical parameters.
Aus dem Inhalt
Chapter I. Introduction: weak non-covalent interactions.
Chapter II. Brief summery on hydrogen-bonded systems: definitions and general view.
Chapter III. Concept of dihydrogen bonding.
Chapter IV. How to find a dihydrogen bond: experimental criteria of the dihydrogen bond formation.
Chapter V. Intramolecular dihydrogen bonds: the theory and experiments.
Chapter VI. Intermolecular dihydrogen-bonded complexes: from group 1A to group 4A and the xenon dihydrogen-bonded complexes.
Chapter VII. Intermolecular dihydrogen bonding in transition metal hydride complexes: bonds.
Chapter VIII. Correlation relationships for intermolecular dihdyrogen bonds.
Chapter IX. Perspectives of dihydrogen bonding in supramolecular chemistry and crystal engineering.
Chapter X. Dihydrogen bonds as intermediates in intermolecular proton transfer reactions.
XI. General conclusion.
Subject Index.
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