1. Auflage - Februar 2005
410,- Euro
2005. 836 Seiten, Hardcover
ISBN-10: 0-470-85062-0
ISBN-13: 978-0-470-85062-6 - John Wiley & Sons

Preis inkl. Mehrwertsteuer zzgl. Versandkosten.





Probekapitel

Kurzbeschreibung
Additives in Polymers defines the strategy for complex analytical problem solving and provides the latest information on sample handling, extractive polymer/additive analysis, chromatographic, spectroscopic, and mass spectrometric methods. Organized for quick, easy reference (with a separate (sub) chapter for each technique), this resource provides comprehensive coverage of the current status of the (qualitative and quantitative) analysis techniques for additive determination in commercial polymers, from the lowest level of analytical sophistication (identification in the bulk) to the highest levels (spatially resolved analysis in relation to migration and physical distribution).

Aus dem Inhalt
Foreword.

Preface.

About the Author.

Acknowledgements.

Chapter 1: Introduction.

1.1 Additives.

1.2 Plastics formulations .

1.3 Economic impact of polymer additives.

1.4 Analysis of plastics.

1.5 Bibliography.

1.6 References.

Chapter 2: Deformulation Principles.

2.1 Polymer identification.

2.2 Additive analysis of rubbers: 'Best Practice'.

2.3 Polymer extract analysis.

2.4 In situ polymer/additive analysis.

2.5 Class-specific polymer/additive analysis.

2.6 Bibliography.

2.7 References.

Chapter 3: Sample Preparation Perspectives.

3.1 Solvents.

3.2 Extraction strategy.

3.3 Conventional extraction technologies.

3.4 High-pressure solvent extraction methods.

3.5 Sorbent extraction.

3.6 Methodological comparison of extraction methods.

3.7 Polymer/additive dissolution methods.

3.8 Hydrolysis.

3.9 Bibliography.

3.10 References.

Chapter 4: Separation Techniques.

4.1 Analytical detectors.

4.2 Gas chromatography.

4.3 Supercritical fluid chromatography.

4.4 Liquid chromatography techniques.

4.5 Capillary electrophoretic techniques.

4.6 Bibliography.

4.7 References.

Chapter 5: Polymer/Additive Analysis: The Spectroscopic Alternative.

5.1 Ultraviolet/visible spectrophotometry.

5.2 Infrared spectroscopy.

5.3 Luminescence spectroscopy.

5.4 High-resolution nuclear magnetic resonance spectroscopy.

5.5 Bibliography.

5.6 References.

Chapter 6: Organic Mass-Spectrometric Methods.

6.1 Basic instrumentation.

6.2 Ion sources.

6.3 Mass analysers.

6.4 Direct mass-spectrometric polymer compound analysis.

6.5 Ion mobility spectrometry.

6.6 Bibliography.

6.7 References.

Chapter 7: Multihyphenation and Multidimensionality in Polymer/Additive Analysis.

7.1 Precolumn hyphenation.

7.2 Coupled sample preparation - spectroscopy/spectrometry.

7.3 Postcolumn hyphenation.

7.4 Multidimensional chromatography.

7.5 Multidimensional spectroscopy.

7.6 Bibliography.

7.7 References.

Chapter 8: Inorganic and Element Analytical Methods.

8.1 Element analytical protocols.

8.2 Sample destruction for classical elemental analysis.

8.3 Analytical atomic spectrometry.

8.4 X-ray spectrometry.

8.5 Inorganic mass spectrometry.

8.6 Radioanalytical and nuclear analytical methods.

8.7 Electroanalytical techniques.

8.8 Solid-state speciation analysis.

8.9 Bibliography.

8.10 References.

Chapter 9: Direct Methods of Deformulation of Polymer/Additive Dissolutions.

9.1 Chromatographic methods.

9.2 Spectroscopic techniques.

9.3 Mass-spectrometric methods.

9.4 References.

Chapter 10: A Vision for the Future.

10.1 Trends in polymer technology.

10.2 Trends in additive technology.

10.3 Environmental, legislative and regulatory constraints.

10.4 Analytical consequences.

10.5 Epilogue.

10.6 Bibliography.

10.7 References.

Appendix I: List of Symbols.

Appendix II: Functionality of Common Additives Used in Commercial Thermoplastics, Rubbers and Thermosetting Resins.

Appendix III: Specimen Polymer Additives Product Sheets.

Index.