|  | Ding, Kuiling / Dai, Li-Xin (eds.)
Organic Chemistry - Breakthroughs and Perspectives
 1. Edition August 2012
99.- Euro
2012. LI, 802 Pages, Softcover
592 Fig. (42 Colored Fig.), 12 Tab.
- Textbook -
ISBN 978-3-527-32963-2 - Wiley-VCH, Weinheim
Also available as Hardcover. |
Content
Sample Chapter
Index
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| Short description
This handy book presents the major developments over the past decade, such as C-H activation, organocatalysis, and supramolecular chemistry. Each chapter contains two or three personal commentaries by leading experts on the topic, previously unpublished.
From the contents
INTRODUCTION
DIVERSITY-ORIENTED SYNTHESES OF NATURAL PRODUCTS AND NATURAL PRODUCT-LIKE COMPOUNDS
Introduction
Diversity-Oriented Synthesis (DOS)
Diverted Total Synthesis (DTS)
Function-Oriented Synthesis (FOS)
Target-Oriented Synthesis (TOS)
Conclusion and Perspectives
TOTAL SYNTHESIS OF NATURAL PRODUCTS AND THE SYNERGY WITH SYNTHETIC METHODOLOGY
Introduction
Domino Process
Multicomponent Reactions
Oxidative Anion Coupling
Pattern Recognition
Conformation-Directed Cyclization
Conclusion and Perspectives
INTERPLAY BETWEEN THE CHEMICAL SPACE AND THE BIOLOGICAL SPACE
Chemical Biology: Historical and Philosophical Aspects
Preparation of Chemical Libraries
Screening Strategies
Target Elucidation and Validation
Conclusion and Perspectives
BIOSYNTHESIS OF PHARMACEUTICAL NATURAL PRODUCTS AND THEIR PATHWAY ENGINEERING
Introduction
Expanded Paradigms in Biosynthetic Logic
New Approaches to NP Biosynthesis Research
Better Understanding of the Scope and Diversity of NP Production
Future Perspectives
CARBOHYDRATE SYNTHESIS TOWARDS GLYCOBIOLOGY
Introduction
Advances in Chemical Glycosylation
New Strategies in Oligosaccharide Assembly
Enzymatic and Chemoenzymatic Methods
Synthesis of Heparin and Heparan Sulfate Oligosaccharides
Synthesis of Homogeneous Glycoproteins
Synthesis of Carbohydrate-Containing Complex Natural Compounds
Conclusion and Perspectives
CHEMICAL SYNTHESIS OF PROTEINS
Introduction
Brief History
Current Technology
Applications
Conclusion and Perspectives
CUAAC: THE QUINTESSENTIAL CLICK REACTION
Introduction
Azide - Alkyne Cycloaddition: the Basics
CuAAC: Catalysts and Ligands
Mechanistic Aspects of the CuAAC
Reactions of 1-Iodoalkynes
Examples of Application of the CuAAC Reaction
Reactions of Sulfonyl Azides
Outlook/Perspective
TRANSITION METAL-CATALYZED C - H FUNCTIONALIZATION: SYNTHETICALLY ENABLING REACTIONS FOR BUILDING MOLECULAR COMPLEXITY
Introduction
Background and Early Work
First Functionalization: Challenges in Hydrocarbon Chemistry
Further Functionalization: C - H Bonds as Reaction Partners in Organic Synthesis
Catalytic C - H Functionalization via Metal Insertion
Other Emerging Metal-Catalyzed Further Functionalization Methods
Outlook and Conclusion
AN OVERVIEW OF RECENT DEVELOPMENTS IN METAL-CATALYZED ASYMMETRIC TRANSFORMATIONS
Introduction
Asymmetric Carbon - Carbon Bond Formation
Asymmetric Reductions and Oxidations
Conclusion
THE PROLINE-CATALYZED MANNICH REACTION AND THE ADVENT OF ENAMINE CATALYSIS
Introduction
The Proline-Catalyzed Mannich Reaction
Conclusion
RECENT TOPICS IN COOPERATIVE CATALYSIS: ASYMMETRIC CATALYSIS, POLYMERIZATION, HYDROGEN ACTIVATION, AND WATER SPLITTING
Introduction
Cooperative Catalysis in Asymmetric Reactions
Cooperative Catalysis in Alkene Polymerization
Cooperative Catalysis in Hydrogen Activation/Generation
Conclusion and Perspectives
FLOURISHING FRONTIERS IN ORGANOFLUORINE CHEMISTRY
Introduction
Synthetic Approaches for the Introduction of Fluorine-Containing Functionalities and Related Chemistry
Conclusion and Perspectives
SUPRAMOLECULAR ORGANIC CHEMISTRY: THE FOLDAMER APPROACH
Introduction
Foldamers: the Background
Molecular Recognition
Homoduplex
Organogels
Vesicles
Supramolecular Liquid Crystals
Macrocycles
Catalysis
Macromolecular Self-Assembly
Conclusion and Perspectives
NOVEL CATALYSIS FOR ALKENE POLYMERIZATION MEDIATED BY POST-METALLOCENES: A GATEWAY TO NEW POLYALKENES
Introduction
Late Transition Metal Complexes
Early Transition Metal Complexes
Conclusion and Perspectives
CHEMISTRY COMPUTATIONALLY AND EXPERIMENTALLY: HOW WILL COMPUTATIONAL ORGANIC CHEMISTRY IMPACT ORGANIC THEORIES, MECHANISMS, AND SYNTHESIS IN THE TWENTY-FIRST CENTURY?
Introduction
Developing New Theories, Concepts, and Understandings for Organic Chemistry
Understanding Reaction Mechanisms
Computation-Guided Development of New Catalysts, New Reactions, and Synthesis Planning for Ideal Synthesis
Conclusion
CASE STUDY OF MECHANISMS IN SYNTHETIC REACTIONS
Introduction
Mechanistic Study of Coupling Reactions
Mechanistic Study of Aerobic Oxidation
Conclusion and Perspective
ORGANIC MATERIALS AND CHEMISTRY FOR BULK HETEROJUNCTION SOLAR CELLS
Introduction
Molecular Design and Engineering of Donor Materials
Molecular Design and Engineering of Acceptor Materials
Conclusion and Outlook
CATALYTIC UTILIZATION OF CARBON DIOXIDE: ACTUAL STATUS AND PERSPECTIVES
Introduction
Catalytic Reductions of CO2 to Formic Acid and Methanol
CO2 as a C1-Building Block in C - C Coupling Reactions
Catalytic C - O Bond Formation Utilizing Carbon Dioxide
Current Industrial Processes Using CO2
Conclusion and Outlook
SYNTHETIC CHEMISTRY WITH AN EYE ON FUTURE SUSTAINABILITY
Introduction
Cross-Dehydrogenative Coupling
Nucleophilic Addition of Terminal Alkynes in Water
Conclusion and Perspectives
ORGANIC Pi-CONJUGATED MOLECULES FOR ORGANIC SEMICONDUCTORS AND PHOTOVOLTAIC MATERIALS
Introduction
Conjugated Molecules for p-Type Organic Semiconductors
Conjugated Molecules for n-Type Organic Semiconductors
Conjugated Molecules for Photovoltaic Materials
Conclusion and Outlook
THE FUTURE OF ORGANIC CHEMISTRY - AN ESSAY
Introduction
The Field of Organic Chemistry Will Broaden
Conclusion
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