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Mesoporous Materials

Interest in mesoporous materials (IUPAC definition: pore size 2–50 nm) has developed dramatically over the last few years, not least because the pore structure of these materials provides an extremely large surface area within a relatively small volume of material. This makes the materials suitable, for example, for catalysis, chemical sensors, and molecular separation.

The following is a selection of recent articles in this field from Angewandte Chemie, Chemistry—A European Journal, Advanced Materials, Advanced Functional Materials, and the European Journal of Inorganic Chemistry.

Recent Articles

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Thin Heterojunctions and Spatially Separated Cocatalysts To Simultaneously Reduce Bulk and Surface Recombination in Photocatalysts

Thin Heterojunctions and Spatially Separated Cocatalysts To Simultaneously Reduce Bulk and Surface Recombination in Photocatalysts

Mesoporous hollow spheres with the composition Pt@TiO2@In2O3@MnOx can absorb both UV and visible light. Owing to the presence of thin heterojunctions and spatially separated cocatalysts, charge recombination is efficiently reduced in both the bulk phase and the surface/subsurface. These hollow spheres can be used as efficient photocatalysts for water and alcohol oxidation.

[Communication]
Ang Li, Xiaoxia Chang, Zhiqi Huang, Chengcheng Li, Yijia Wei, Lei Zhang, Tuo Wang, Jinlong Gong
Angew. Chem. Int. Ed., July 22, 2016, DOI: 10.1002/anie.201605666. Read article

A Luminescent Zinc(II) Metal–Organic Framework for Selective Detection of Nitroaromatics, Fe3+ and CrO42−: A Versatile Threefold Fluorescent Sensor

A Luminescent Zinc(II) Metal–Organic Framework for Selective Detection of Nitroaromatics, Fe3+ and CrO42−: A Versatile Threefold Fluorescent Sensor

Explosive-controlled afterglow: A new Zn metal–organic framework contains two distinct types of pores (A & B) and displays selective detection, through photoluminescence quenching, of nitrobenzene, a precursor for explosives, as well as CrO42− and Fe3+ ions.

[Full Paper]
Bao-Hong Li, Jian Wu, Jian-Qiang Liu, Chu-Ying Gu, Jing-Wen Xu, Miao-Miao Luo, Reena Yadav, Abhinav Kumar, Stuart R. Batten
ChemPlusChem, July 21, 2016, DOI: 10.1002/cplu.201600304. Read article

Design and Synthesis of a Water-Stable Anionic Uranium-Based Metal–Organic Framework (MOF) with Ultra Large Pores

Design and Synthesis of a Water‐Stable Anionic Uranium‐Based Metal–Organic Framework (MOF) with Ultra Large Pores

Stuck on U: Large cationic dyes and enzymes are adsorbed selectively over their anionic counterparts by a water-stable anionic mesoporous metal–organic framework (MOF) based on uranium.

[Communication]
Peng Li, Nicolaas A. Vermeulen, Xirui Gong, Christos D. Malliakas, J. Fraser Stoddart, Joseph T. Hupp, Omar K. Farha
Angew. Chem. Int. Ed., July 21, 2016, DOI: 10.1002/anie.201605547. Read article

Tunable-Sized Polymeric Micelles and Their Assembly for the Preparation of Large Mesoporous Platinum Nanoparticles

Tunable‐Sized Polymeric Micelles and Their Assembly for the Preparation of Large Mesoporous Platinum Nanoparticles

Dancing to a different tune: Platinum nanoparticles with continuously tunable mesoporous structures were prepared by a one-step approach based on polymeric micelles. Their particle and pore sizes were controlled by altering the solvent composition (see picture). By virtue of their high surface area, these mesoporous Pt structures were more efficient electrocatalysts for methanol oxidation than commercially available Pt catalysts.

[Communication]
Bo Jiang, Cuiling Li, Jing Tang, Toshiaki Takei, Jung Ho Kim, Yusuke Ide, Joel Henzie, Satoshi Tominaka, Yusuke Yamauchi
Angew. Chem. Int. Ed., July 21, 2016, DOI: 10.1002/anie.201603967. Read article

MOFsome via Transient Pickering Emulsion Template

MOFsome via Transient Pickering Emulsion Template

A top-down transient Pickering emulsion templating method is introduced to prepare MOFsomes (metal–organic framework colloidosomes) with a multilayer-shell spherical hollow structure. It is also demonstrated that this type of MOFsomes can be employed as a platform to prepare multicomponent and multifunctional colloidosomes by introducing different types of particles.

[Communication]
He Zhu, Qi Zhang, Shiping Zhu
Adv. Mater. Interfaces, July 20, 2016, DOI: 10.1002/admi.201600294. Read article

Metal-Organic-Framework-Based Vaccine Platforms for Enhanced Systemic Immune and Memory Response

Metal‐Organic‐Framework‐Based Vaccine Platforms for Enhanced Systemic Immune and Memory Response

In this paper, metal-organic-framework (MOF) based vaccines are fabricated facilely to deliver protein antigens and adjuvants in the same antigen presenting cells. Both in vitro and in vivo experiments demonstrate that the nanocomposites can induce strong humoral, cellular immunity, and potent immune memory response. The MOF-based vaccine platform can be useful for the prevention and/or therapy of various diseases.

[Full Paper]
Yan Zhang, Faming Wang, Enguo Ju, Zhen Liu, Zhaowei Chen, Jinsong Ren, Xiaogang Qu
Adv. Funct. Mater., July 19, 2016, DOI: 10.1002/adfm.201600650. Read article

Efficient synthesis and tailoring of magnetic and dielectric properties of Pb-free perovskite-like ABX3 metal-organic frameworks

Efficient synthesis and tailoring of magnetic and dielectric properties of Pb‐free perovskite‐like ABX3 metal‐organic frameworks

Perovskite-like multiferroic metal-organic frameworks (MOFs) with the general formula ABX3 were synthesized by a microwave-assisted protocol, resulting in >100-fold increase in the efficiency of synthesis. The parameters of the synthesis were used to realize control over the size and morphology of the particles formed. The evolution of magnetic and electric properties was studied as a function of particle size.

[Rapid Research Letter]
Nandita Abhyankar, Minseong Lee, Megan Foley, Eun Sang Choi, Geoffrey Strouse, Harold W. Kroto, Naresh S. Dalal
Phys. Status Solidi RRL, July 18, 2016, DOI: 10.1002/pssr.201600175. Read article

Polarity Control at Interfaces: Quantifying Pseudo-Solvent Effects in Confined Systems

Surface functionalization controls local environments and induces solvent-like effects at liquid-solid interfaces. We explored structure-property relationships between organic groups bound to pore surfaces of mesoporous silica nanoparticles and Stokes shifts of adsorbed solvatochromic dye Prodan. Correlating shifts of the dye on the surfaces with its shifts in solvents resulted in a local polarity scale for functionalized pores. The scale was validated by studying the effects of pore polarity on quenching of Nile Red fluorescence and on the vibronic band structure of pyrene. Measurements were done in aqueous suspensions of porous particles, proving that the dielectric properties in the pores are different from the bulk solvent. The precise control of pore polarity was used to enhance the catalytic activity of TEMPO in the aerobic oxidation of furfuryl alcohol in water. An inverse relationship was found between pore polarity and activity of TEMPO in the pores, demonstrating that controlling the local polarity around an active site allows modulating the activity of nanoconfined catalysts.

[Communication]
Dilini Singappuli-Arachchige, Sebastian Manzano, Lindy Sherman, Igor I. Slowing
ChemPhysChem, July 18, 2016, DOI: 10.1002/cphc.201600740. Read article

In Situ Synthesis of Metal Sulfide Nanoparticles Based on 2D Metal-Organic Framework Nanosheets

In Situ Synthesis of Metal Sulfide Nanoparticles Based on 2D Metal‐Organic Framework Nanosheets

A facile in situ synthetic method is developed to synthesize metal sulfide nanoparticles based on 2D M-TCPP (M = Cu, Cd, or Co, TCPP = tetrakis(4-carboxyphenyl)porphyrin)) metal-organic framework nanosheets. The obtained CuS/Cu-TCPP composite nanosheet is used as the active material in photoelectrochemical cells, showing notably increased photocurrent due to the improved exciton separation and charge carrier transport.

[Communication]
Qipeng Lu, Meiting Zhao, Junze Chen, Bo Chen, Chaoliang Tan, Xiao Zhang, Ying Huang, Jian Yang, Feifei Cao, Yifu Yu, Jianfeng Ping, Zhicheng Zhang, Xue-Jun Wu, Hua Zhang
Small, July 14, 2016, DOI: 10.1002/smll.201600976. Read article

Effectively Improving Capacitive Performance of Three-Dimensional Iron(III) Oxide Nanotube Arrays by Rationally Filling Mesopores with Polypyrrole

Effectively Improving Capacitive Performance of Three‐Dimensional Iron(III) Oxide Nanotube Arrays by Rationally Filling Mesopores with Polypyrrole

Fill ’er up! The capacitive performances of 3D Fe2O3 nanotube arrays are dramatically improved by partly filling their mesopores with polypyrrole (PPy). Although the filled PPy accounts for only 9.7 wt %, the resulting hybrid Fe2O3/PPy arrays triple the specific capacitance and double the rate capability of Fe2O3 arrays and, furthermore, exhibit good cycling stability at high current density.

[Article]
Zhikui Wang, Qinmin Pan
ChemElectroChem, July 14, 2016, DOI: 10.1002/celc.201600244. Read article

Metal–Organic Framework Coatings as Cytoprotective Exoskeletons for Living Cells

Metal–Organic Framework Coatings as Cytoprotective Exoskeletons for Living Cells

The biomimetic mineralization of metal–organic framework (MOF) material on living cells is reported. ZIF-8 can be crystallized on a living cell surface as an exoskeleton that offersphysical protection while allowing transport of essential nutrients, thus maintaining cell viability. The MOF shell prevents cell division, leading to an artificially induced pseudo-hibernation state. Cellular functions can be fully restored upon MOF removal.

[Communication]
Kang Liang, Joseph J. Richardson, Jiwei Cui, Frank Caruso, Christian J. Doonan, Paolo Falcaro
Adv. Mater., July 14, 2016, DOI: 10.1002/adma.201602335. Read article

A Reusable Mesoporous Nickel Nanocomposite Catalyst for the Selective Hydrogenation of Nitroarenes in the Presence of Sensitive Functional Groups

A Reusable Mesoporous Nickel Nanocomposite Catalyst for the Selective Hydrogenation of Nitroarenes in the Presence of Sensitive Functional Groups

Why so sensitive? A novel mesostructured Ni nanocomposite catalyst that is easy to synthesize and scale up is introduced. It is a reusable catalyst for the selective hydrogenation of nitroarenes to anilines. Highly hydrogenation-sensitive groups such as olefins and aldehydes are tolerated.

[Communication]
Gabriela Hahn, Julia-Katharina Ewert, Christine Denner, Dominic Tilgner, Rhett Kempe
ChemCatChem, July 08, 2016, DOI: 10.1002/cctc.201600391. Read article

Imidazolyl-Functionalized Ordered Mesoporous Polymer from Nanocasting as an Effective Support for Highly Dispersed Palladium Nanoparticles in the Heck Reaction

Imidazolyl‐Functionalized Ordered Mesoporous Polymer from Nanocasting as an Effective Support for Highly Dispersed Palladium Nanoparticles in the Heck Reaction

Order, order! An ordered mesoporous polymer, which benefits from the use of entrapped ionic liquid in a new polymer matrix in combination with its ordered mesoporous structure, is an excellent environment for the stabilization of highly dispersed Pd nanoparticles in the Heck reaction of various aryl halides.

[Full Paper]
Babak Karimi, Mohammad Reza Marefat, Maliheh Hasannia, Pari Fadavi Akhavan, Fariborz Mansouri, Zahra Artelli, Fariba Mohammadi, Hojatollah Vali
ChemCatChem, July 07, 2016, DOI: 10.1002/cctc.201600630. Read article

Non-Precious Metal Catalysts Prepared By Zeolitic Imidazolate Frameworks: The Ligand Influence to Morphology and Performance

[Original Research Paper]
H. M. Barkholtz, L. Chong, Z. B. Kaiser, D. J. Liu
Fuel Cells, July 06, 2016, DOI: 10.1002/fuce.201500164. Read article

Endocytosis Mechanism of Nano Metal-Organic Frameworks for Drug Delivery

Endocytosis Mechanism of Nano Metal‐Organic Frameworks for Drug Delivery

The study of the uptake mechanisms and final fate of a promising metal-organic framework (MOF) is a crucial step for optimizing these materials for drug delivery applications. UiO-66 particles of 260 nm are able to partially bypass the acidic degradation in the lysosomes whereas particles of 150 nm are destroyed in this compartment.

[Full Paper]
Claudia Orellana-Tavra, Sergio A. Mercado, David Fairen-Jimenez
Adv. Healthcare Mater., July 06, 2016, DOI: 10.1002/adhm.201600296. Read article

Lightweight Ionic Networks Composed of Li+ or Mg2+ Centres Linked Together by Dicarboxylate Ligands

Lightweight Ionic Networks Composed of Li+ or Mg2+ Centres Linked Together by Dicarboxylate Ligands

Let′s link up: Dicarboxylate ligands have been used to link metal centres such as Li+ and Mg2+ to form 3 D networks (see figure) in which solvent is located in the channels. One of the lithium-based networks exhibits significant hysteresis in its adsorption of CO2 whilst an anionic magnesium network is able to exchange its Li+ countercations for Fe(2,2-bipyridine)32+.

[Full Paper]
Keith F. White, Brendan F. Abrahams, Timothy A. Hudson, Richard Robson
ChemPlusChem, July 05, 2016, DOI: 10.1002/cplu.201600274. Read article

Emissive Heterobimetallic Copper(I) Dicyanoaurate-Based Coordination Polymers

Emissive Heterobimetallic Copper(I) Dicyanoaurate‐Based Coordination Polymers

Show your colors! Emissive CuI/L/[Au(CN)2] (L=py, PPh3, THT) materials were synthesized and characterized. Neither Cu(py)2[Au(CN)2] nor Cu(PPh3)(MeCN)[Au(CN)2] contain Au⋅⋅⋅Au interactions while Cu3(THT)4[Au(CN)2]3 and Cu(THT)[Au(CN)2] feature them in abundance. Each material exhibits a unique emission colour (see figure). py=pyridine, THT=tetrahydrothiophene.

[Full Paper]
Jeffrey S. Ovens, Daniel B. Leznoff
ChemPlusChem, July 05, 2016, DOI: 10.1002/cplu.201600228. Read article

Cover Picture: A New Paddlewheel-Type Dirhodium-Based Metal-Organic Framework with Deprotonated 2,6-Bis(2-benzimidazolyl)pyridine (ChemistrySelect 11/2016)

Cover Picture: A New Paddlewheel‐Type Dirhodium‐Based Metal‐Organic Framework with Deprotonated 2,6‐Bis(2‐benzimidazolyl)pyridine (ChemistrySelect 11/2016)

The cover picture shows an artist's representation of the porous metal-organic framework (MOF) constructed from paddlewheel-type dirhodium tetracetate and 2,6-bis(2-benzimidazolyl)pyridine and an intermediate complex in the middle of formation of the MOF. This MOF shows the color-changing behavior from orange-red to yellow-brown depending on the structural decomposition due to the removal of guest solvents from the pores of MOF. The decomposed MOF is easily recovered to the porous MOF by soaking in ethanol. More information can be found in the Full Paper by Yusuke Kataoka, Natsumi Yano, et al. (DOI: 10.1002/slct.201600617).

[Cover Picture]
Natsumi Yano, Yusuke Kataoka, Hidekazu Tanaka, Tatsuya Kawamoto, Makoto Handa
ChemistrySelect, June 30, 2016, DOI: 10.1002/slct.201600725. Read article

A New Paddlewheel-Type Dirhodium-Based Metal-Organic Framework with Deprotonated 2,6-Bis(2-benzimidazolyl)pyridine

A New Paddlewheel‐Type Dirhodium‐Based Metal‐Organic Framework with Deprotonated 2,6‐Bis(2‐benzimidazolyl)pyridine

Two different crystals, orange-red chips (1) and purple blocks (2), are obtained via the solvothermal reaction of [Rh2(OAc)4(H2O)2] (OAc=acetate) and 2,6-bis(2-benzimidazolyl)pyridine (bzimpy2H) in EtOH. Single crystal X-ray diffraction analyses revealed that complex 1 forms a porous two-dimensional framework constructed from [Rh2(OAc)4] and [Rh(bzimpyH)(bzimpy)], whereas complex 2 forms a bis-bzimpy2H-adducted discrete complex, [Rh2(OAc)4(bzimpy2H)2]. Complex 2 shows the color-changing behavior due to the presence of the guest solvents in the pores.

[Full Paper]
Natsumi Yano, Yusuke Kataoka, Hidekazu Tanaka, Tatsuya Kawamoto, Makoto Handa
ChemistrySelect, June 30, 2016, DOI: 10.1002/slct.201600617. Read article

Separation of Light Hydrocarbons through Selective Molecular Exclusion by a Microporous Metal–Organic Framework

Separation of Light Hydrocarbons through Selective Molecular Exclusion by a Microporous Metal–Organic Framework

Sorting out: A new Zn-based pillared-layer microporous metal–organic framework undergoes structural change upon solvent removal. The resulting phase is capable of separating light hydrocarbons by selective molecular exclusion (see figure).

[Full Paper]
Hao Wang, Xin-Long Wang, Jing Li
ChemPlusChem, June 30, 2016, DOI: 10.1002/cplu.201600259. Read article

High-Performance Hybrid Supercapacitor Based on Graphene-Wrapped Mesoporous T-Nb2O5 Nanospheres Anode and Mesoporous Carbon-Coated Graphene Cathode

High‐Performance Hybrid Supercapacitor Based on Graphene‐Wrapped Mesoporous T‐Nb2O5 Nanospheres Anode and Mesoporous Carbon‐Coated Graphene Cathode

Best of both: Nonaqueous high-performance lithium-ion hybrid supercapacitors (Li-HSCs) are fabricated by using reduced graphene oxide cross-linked mesoporous T-Nb2O5 nanospheres (T-Nb2O5 MNSs/rGO) as Li+ intercalation pseudocapacitive material and mesoporous carbon-coated rGO as electric double-layer capacitive material. The Li-HSC exhibits a high energy density of 56 Wh kg−1, a power density of 25 600 W kg−1, as well as excellent cycling stability.

[Article]
Guoqiang Ma, Ke Li, Yuanyuan Li, Biao Gao, Tianpeng Ding, Qize Zhong, Jun Su, Li Gong, Jian Chen, Longyan Yuan, Bin Hu, Jun Zhou, Kaifu Huo
ChemElectroChem, June 27, 2016, DOI: 10.1002/celc.201600181. Read article

Carbon Dioxide Reforming of Methane over Cobalt-Nickel Bimetal-Doped Ordered Mesoporous Alumina Catalysts with Advanced Catalytic Performances

Carbon Dioxide Reforming of Methane over Cobalt‐Nickel Bimetal‐Doped Ordered Mesoporous Alumina Catalysts with Advanced Catalytic Performances

Ordered mesoporous Co-Ni bimetallic catalysts: A series of Co-Ni bimetal-doped ordered mesoporous Al2O3 composite oxides with excellent textural properties and thermal stability is synthesized by a one-pot evaporation-induced self-assembly method and utilized as catalysts for the CO2 reforming of CH4. The Co-Ni synergistic effect and ordered mesostructure play significant roles to improve the catalytic properties and coke resistance of the materials.

[Full Paper]
Leilei Xu, Fagen Wang, Mindong Chen, Jian Zhang, Kaidi Yuan, Liangjun Wang, Kai Wu, Guoqin Xu, Wei Chen
ChemCatChem, June 22, 2016, DOI: 10.1002/cctc.201600472. Read article

Metal-Organic Gel Material Based on UiO-66-NH2 Nanoparticles for Improved Adsorption and Conversion of CO2

Metal-organic frameworks (MOFs) including UiO-66 series show potential application in CO2 adsorption and conversion. Herein, we report the first tetravalent metal-based metal-organic gels based on Zr(IV) and 2-aminoterephthalic acid (H2BDC-NH2). ZrBDC-NH2 gel materials are based on UiO-66-NH2 nanoparticles, and can be easily prepared under mild conditions (80 oC for 4.5 h). ZrBDC-NH2-1:1-0.2 gel material shows high surface area (up to 1040 m2 g-1). ZrBDC-NH2-1:1-0.2 has a superior performance in CO2 adsorption (using dried material) and conversion (using wet gel) arising from its combined advantages of gels and UiO-66-NH2 MOF. ZrBDC-NH2-1:1-0.2 dried material shows 38% higher capture capacity for CO2 at 298 K than microcrystalline UiO-66-NH2. It shows high IAST selectivity (71.6 at 298 K) for a CO2/N2 gas mixture (molar ratio 15 : 85). Furthermore ZrBDC-NH2-1:1-0.2 gel shows activity as a heterogeneous catalyst in chemical fixation of CO2 and an excellent catalytic performance was achieved for the cycloaddition of atmospheric pressure of CO2 to epoxides under 373 K. In addition, the gel catalyst can be reused for multiple cycles and no considerable loss of catalytic activity was observed after five runs.

[Full Paper]
Liping Liu, Jianyong Zhang, Haobin Fang, Liuping Chen, Cheng-Yong Su
Chem. Asian J., June 22, 2016, DOI: 10.1002/asia.201600698. Read article

Ordered Mesoporous Polyoxometalate–Organosilica Frameworks as Efficient Photocatalysts of the Hydrogen Evolution Reaction

Ordered Mesoporous Polyoxometalate–Organosilica Frameworks as Efficient Photocatalysts of the Hydrogen Evolution Reaction

Better for HER: Mesoporous polyoxometalate-based organosilica framework materials, featuring ordered pore structure, high density of exposed active sites and large internal surface area, catalyze relatively high H2 production with remarkable cycling stability (see figure). The H2 evolution reaction activity was achieved without the use of precious metals as co-catalysts or additional photosensitizers.

[Full Paper]
Eirini D. Koutsouroubi, Ioannis T. Papadas, Gerasimos S. Armatas
ChemPlusChem, June 17, 2016, DOI: 10.1002/cplu.201600199. Read article

Metal–Organic Frameworks M-MOF-74 and M-MIL-100: Comparison of Textural, Acidic, and Catalytic Properties

Metal–Organic Frameworks M‐MOF‐74 and M‐MIL‐100: Comparison of Textural, Acidic, and Catalytic Properties

Finding open sites: Two families of metal–organic frameworks (MOFs; MII-MOF-74 and MIII-MIL-100; MII=Co, Cu, Mg, Ni; MIII=Al, Cr, Sc, V) are synthesized and compared in the tetrahydropyranylation of alcohols of different sizes (see figure). A combination of superior textural properties with the accessibility and strength of open metal sites in V-MIL-100 lead to the best catalytic performance of the MOFs studied.

[Full Paper]
Carlos Palomino Cabello, Gema Gómez-Pozuelo, Maksym Opanasenko, Petr Nachtigall, Jiří Čejka
ChemPlusChem, June 17, 2016, DOI: 10.1002/cplu.201600168. Read article

Direct Evidence of CO2 Capture under Low Partial Pressure on a Pillared Metal–Organic Framework with Improved Stabilization through Intramolecular Hydrogen Bonding

Direct Evidence of CO2 Capture under Low Partial Pressure on a Pillared Metal–Organic Framework with Improved Stabilization through Intramolecular Hydrogen Bonding

Capturing carbon dioxide: FJU-40-NH2 is shown to be the first MOF for which the stability is controlled through intramolecular hydrogen-bonding interactions. Direct structural evidence obtained under low CO2 partial pressure suggests that: 1) the CO2 loading mechanism into the cages depends on CO2 partial pressure; 2) FJU-40-NH2 can capture CO2 directly from air (see figure); and 3) the triazolate C−H groups, rather than amino groups, are the predominant functional sites here.

[Full Paper]
Zizhu Yao, Yuan Chen, Lizhen Liu, Xiaonan Wu, Shunshun Xiong, Zhangjing Zhang, Shengchang Xiang
ChemPlusChem, June 17, 2016, DOI: 10.1002/cplu.201600156. Read article

Poly(ethylenimine)-Functionalized Monolithic Alumina Honeycomb Adsorbents for CO2 Capture from Air

Poly(ethylenimine)‐Functionalized Monolithic Alumina Honeycomb Adsorbents for CO2 Capture from Air

Clean air powder: Amine-functionalized honeycomb monoliths are prepared, characterized, and compared to similar powder sorbents for their application in the removal of CO2 from air. The monoliths have a volumetric capacity that exceeds that of a sorbent considered in a previous modeling study. CO2 extraction directly from air with chemicals could have operating costs as low as $100 per ton, which thus asserts the promise of this technology in CO2 extraction directly from air with chemicals.

[Full Paper]
Miles A. Sakwa-Novak, Chun-Jae Yoo, Shuai Tan, Fereshteh Rashidi, Christopher W. Jones
ChemSusChem, June 15, 2016, DOI: 10.1002/cssc.201600404. Read article

A Base-Resistant ZnII-Based Metal–Organic Framework: Synthesis, Structure, Postsynthetic Modification, and Gas Adsorption

A Base‐Resistant ZnII‐Based Metal–Organic Framework: Synthesis, Structure, Postsynthetic Modification, and Gas Adsorption

If you can stand the heat: A ZnII-based metal–organic framework (MOF), [Zn2(bdp-CHO)2](DMF)(CH3CN)(H2O)2 (BUT-31) was synthesized through the reaction between an aldehyde-tagged polypyrazole ligand 2,5-di(1H-pyrazol-4-yl)benzaldehyde (H2bdp-CHO) and a zinc salt. BUT-31 has a unique pillared layered framework structure with 3D intersecting channels of around 3.4–5.4 Å (see figure). Notably, this MOF tolerates boiling water and even 4 m NaOH, although dilute acid gradually decomposes its framework.

[Full Paper]
Tao He, Yong-Zheng Zhang, Bin Wang, Xiu-Liang Lv, Lin-Hua Xie, Jian-Rong Li
ChemPlusChem, June 15, 2016, DOI: 10.1002/cplu.201600163. Read article

Enhanced Ligand-Based Luminescence in Metal–Organic Framework Sensor

Enhanced Ligand‐Based Luminescence in Metal–Organic Framework Sensor

S-Sensing: The rational design of luminescent metal–organic frameworks (MOFs) coupled with an innovative laser irradiation protocol is reported. This approach gives access to a detection system for endogenously produced sulfide in serum samples for concentrations as low as 100 nm.

[Full Paper]
Alexandre Legrand, Anton Pastushenko, Vladimir Lysenko, Alain Geloen, Elsje Alessandra Quadrelli, Jerome Canivet, David Farrusseng
ChemNanoMat, June 15, 2016, DOI: 10.1002/cnma.201600124. Read article

A Green Approach to High-Performance Supercapacitor Electrodes: The Chemical Activation of Hydrochar with Potassium Bicarbonate

A Green Approach to High‐Performance Supercapacitor Electrodes: The Chemical Activation of Hydrochar with Potassium Bicarbonate

K-OK: A green approach for the production of high-performance energystorage materials based on the activation of hydrochar with potassium bicarbonate is implemented successfully, leading to a supercapacitor performance that can compete with, and even surpass, that of KOH-activated hydrochar in a variety of electrolytes.

[Full Paper]
Marta Sevilla, Antonio B. Fuertes
ChemSusChem, June 07, 2016, DOI: 10.1002/cssc.201600426. Read article

Gadolinium(III)-Based Porous Luminescent Metal–Organic Frameworks for Bimodal Imaging

Gadolinium(III)‐Based Porous Luminescent Metal–Organic Frameworks for Bimodal Imaging

Two for one: Two gadolinium(III)-based fluorescent metal–organic frameworks, Gd-pDBI-1 and Gd-pDBI-2, have been synthesized using the fluorescent linker. These materials are suitable for simultaneous bimodal (fluorescence and magnetic resonance) imaging applications and postsynthetic modifications are not required (see figure).

[Communication]
Tanay Kundu, Shouvik Mitra, David Díaz Díaz, Rahul Banerjee
ChemPlusChem, June 07, 2016, DOI: 10.1002/cplu.201600233. Read article

Thermal and Gas Dual-Responsive Behaviors of an Expanded UiO-66-Type Porous Coordination Polymer

Thermal and Gas Dual‐Responsive Behaviors of an Expanded UiO‐66‐Type Porous Coordination Polymer

Dual-responsive oxygen sensor: By virtue of the long length, simple skeleton, and relatively large π-conjugation system of the organic ligand provided by the ethynyl bridge, an expanded version of the UiO-66-type compound exhibits not only large negative thermal expansion, but also notable oxygen sensing properties (see figure).

[Full Paper]
Hao-Long Zhou, Jie Bai, Jia-Wen Ye, Zong-Wen Mo, Wei-Xiong Zhang, Jie-Peng Zhang, Xiao-Ming Chen
ChemPlusChem, June 07, 2016, DOI: 10.1002/cplu.201600145. Read article

Low Cytotoxic Metal–Organic Frameworks as Temperature-Responsive Drug Carriers

Low Cytotoxic Metal–Organic Frameworks as Temperature‐Responsive Drug Carriers

Drugs on demand: Two low cytotoxicity metal–organic frameworks (MOFs), ZJU-64 and ZJU-64-CH3, have been prepared. The anticancer drug methotrexate (MTX) can be loaded at desirable drug payloads. The drug-loaded crystals exhibit sustainable release and temperature-responsive deliveries to provide a new strategy that combines drug therapy and thermal therapy to advance the therapeutic efficacy (see figure).

[Full Paper]
Wenxin Lin, Quan Hu, Jiancan Yu, Ke Jiang, Yanyu Yang, Shengchang Xiang, Yuanjing Cui, Yu Yang, Zhiyu Wang, Guodong Qian
ChemPlusChem, June 06, 2016, DOI: 10.1002/cplu.201600142. Read article

Chemical Sensors Based on Metal–Organic Frameworks

Chemical Sensors Based on Metal–Organic Frameworks

Come to your sensors! This review provides an update on various metal–organic framework (MOF)-based chemical sensors and their classification on the basis of different mechanisms of luminescent (“turn-on” and “turn-off”) and optoelectronic responses (see figure). There are many examples of turn-off detection, but far fewer of turn-on detection. MOF-based electrochemical sensors, in particular, are in their infancy.

[Review]
Fei-Yan Yi, Dongxiao Chen, Meng-Ke Wu, Lei Han, Hai-Long Jiang
ChemPlusChem, June 02, 2016, DOI: 10.1002/cplu.201600137. Read article

Dopamine-Directed In-Situ and One-Step Synthesis of Au@Ag Core–Shell Nanoparticles Immobilized to a Metal–Organic Framework for Synergistic Catalysis

Dopamine‐Directed In‐Situ and One‐Step Synthesis of Au@Ag Core–Shell Nanoparticles Immobilized to a Metal–Organic Framework for Synergistic Catalysis

There′s a synergy: Bimetallic core–shell Au@Ag NPs were immobilized in MOFs via one-step synthetic route at room temperature by using dopamine (DA) as a moderate reductant to reduce the bimetallic precursors step-by-step spontaneously. The as-formed Au@Ag/MOF composites show a striking synergistic effect for heterogeneous catalysis.

[Communication]
Pengcheng Huang, Wenjie Ma, Ping Yu, Lanqun Mao
Chem. Asian J., June 02, 2016, DOI: 10.1002/asia.201600469. Read article

A Bifunctional Metal–Organic Framework: Striking CO2-Selective Sorption Features along with Guest-Induced Tuning of Luminescence

A Bifunctional Metal–Organic Framework: Striking CO2‐Selective Sorption Features along with Guest‐Induced Tuning of Luminescence

Pay your gas and light utilities! A mixed-linker strategy was used to synthesize a two-dimensional CdII-based luminescent metal–organic framework (LMOF). Owing to its primary-amine-rich Lewis basic voidspace, it exhibits selective CO2 uptake over flue gases, while its highly luminescent constituent linkers generate a dually tunable luminescent response that can serve to detect different phenolic species.

[Communication]
Soumya Mukherjee, Aamod V. Desai, Yogeshwar D. More, Arif I. Inamdar, Sujit K. Ghosh
ChemPlusChem, June 01, 2016, DOI: 10.1002/cplu.201600138. Read article

A Twofold Interpenetrated Metal–Organic Framework with High Performance in Selective Separation of C2H2/CH4

A Twofold Interpenetrated Metal–Organic Framework with High Performance in Selective Separation of C2H2/CH4

Let gas in! A twofold interpenetrated metal–organic framework, PMOF-3, composed of four kinds of polyhedra exhibits a high selectivity of 157 for C2H2/CH4 separation at 296 K and 1 atm owing to the synergistic effect of the open metal sites, C≡C triple bonds, and microporous structure (see figure).

[Full Paper]
Osamah Alduhaish, Hailong Wang, Bin Li, Tong-Liang Hu, Hadi D. Arman, Khalid Alfooty, Banglin Chen
ChemPlusChem, May 31, 2016, DOI: 10.1002/cplu.201600194. Read article

Fe/Fe3C/N-Doped Carbon Materials from Metal–Organic Framework Composites as Highly Efficient Oxygen Reduction Reaction Electrocatalysts

Fe/Fe3C/N‐Doped Carbon Materials from Metal–Organic Framework Composites as Highly Efficient Oxygen Reduction Reaction Electrocatalysts

Either ORR: Fe/Fe3C/N-doped carbon materials were prepared by pyrolyzing a composite that contained a metal–organic framework (MIL-88c-Fe) and dicyandiamide. The carbon material obtained at a pyrolysis temperature of 800 °C showed comparable onset potential and higher current density than Pt/C for ORR catalysis in basic media (see figure). Further experiments proved the important role of Fe-containing sites during ORR catalysis.

[Communication]
Yuhong Qian, Jack Cavanaugh, Inayat Ali Khan, Xuerui Wang, Yongwu Peng, Zhigang Hu, Yuxiang Wang, Dan Zhao
ChemPlusChem, May 31, 2016, DOI: 10.1002/cplu.201600174. Read article

Investigation of Oxygen Reduction Activity of Catalysts Derived from Co and Co/Zn Methyl-Imidazolate Frameworks in Proton Exchange Membrane Fuel Cells

Investigation of Oxygen Reduction Activity of Catalysts Derived from Co and Co/Zn Methyl‐Imidazolate Frameworks in Proton Exchange Membrane Fuel Cells

Smooth operator: The catalytic oxygen reduction reaction activity and durability of nonprecious-metal catalysts derived from cobalt-based monometallic and bimetallic zeolitic imidazolate frameworks are found to be strongly influenced by the imidazole ligand structure and cobalt concentration, as demonstrated by the fuel cell tests under operating conditions.

[Communication]
Lina Chong, Gabriel A. Goenaga, Kia Williams, Heather M. Barkholtz, Lauren R. Grabstanowicz, Jeremy A. Brooksbank, Alex B. Papandrew, Radwan Elzein, Rudiger Schlaf, Thomas A. Zawodzinski, Jianxin Zou, Shengqian Ma, Di-Jia Liu
ChemElectroChem, May 31, 2016, DOI: 10.1002/celc.201600163. Read article

Three Zinc(II) Phosphonates: Syntheses, Structures and Sensing of Copper(II) Ions

Three Zinc(II) Phosphonates: Syntheses, Structures and Sensing of Copper(II) Ions

Diamond in the MOF: Three zinc(II) phosphonocarboxylates have been solvothermally synthesised by using 3-phosphonobenzoic acid as a ligand to generate unique topologies (see figure). Luminescence studies reveal that two compounds could be potential sensors for copper(II) ions.

[Full Paper]
Hongjie He, Peng Zhang, Yun Ling, Zhenxia Chen, Yaming Zhou
ChemPlusChem, May 27, 2016, DOI: 10.1002/cplu.201600146. Read article

Modulation of Gas Sorption Properties through Cation Exchange within an Anionic Metal–Organic Framework

Modulation of Gas Sorption Properties through Cation Exchange within an Anionic Metal–Organic Framework

Guest swap: An anionic metal–organic framework has been synthesized, in which Me2NH2+ can be exchanged by Li+. The results of gas adsorption measurements indicate that the Li+-exchanged material exhibits enhanced gas storage and selective adsorption of CO2 over CH4 and N2 at room temperature (see figure).

[Full Paper]
Yong-Liang Huang, Long Jiang, Tong-Bu Lu
ChemPlusChem, May 27, 2016, DOI: 10.1002/cplu.201600121. Read article

Thermally Driven Dynamics of a Rotaxane Wheel about an Imidazolium Axle inside a Metal–Organic Framework

Thermally Driven Dynamics of a Rotaxane Wheel about an Imidazolium Axle inside a Metal–Organic Framework

The wheels in the MOF go round and round: A new [2]rotaxane linker allows for formation of a MOF framework (UWDM-5) in which there is sufficient void space for the dynamic motions of the interlocked [24]crown-6 ether wheel (see figure). Upon heating, the “soft” ring undergoes a series of conformational changes and rotations about the “rigid” MOF framework.

[Full Paper]
Nasim Farahani, Kelong Zhu, Christopher A. O'Keefe, Robert W. Schurko, Stephen J. Loeb
ChemPlusChem, May 25, 2016, DOI: 10.1002/cplu.201600176. Read article

Microporous Lanthanide Metal–Organic Frameworks with Multiple 1D Channels: Tunable Colors, White-Light Emission, and Luminescent Sensing for Iron(II) and Iron(III)

Microporous Lanthanide Metal–Organic Frameworks with Multiple 1D Channels: Tunable Colors, White‐Light Emission, and Luminescent Sensing for Iron(II) and Iron(III)

Channel swap: A series of isostructural 3D microporous lanthanide metal–organic frameworks (MOFs) with multiple 1D channels were prepared under solvothermal conditions. Upon cation exchange, tunable luminescence and white-light emission were achieved by adjusting the relative amount of Eu3+ and Tb3+ ions encapsulated in the Gd framework (see figure). Moreover, the Eu framework can be explored as a potential luminescent material for sensing metal ions, especially Fe2+ and Fe3+.

[Full Paper]
Zhong-Yuan Zhou, Yun-Hu Han, Xiu-Shuang Xing, Shao-Wu Du
ChemPlusChem, May 24, 2016, DOI: 10.1002/cplu.201600141. Read article

Assembling Metal–Organic Frameworks in Ionic Liquids and Supercritical CO2

Assembling Metal–Organic Frameworks in Ionic Liquids and Supercritical CO2

Being green: Ionic liquids (ILs) and supercritical carbon dioxide (scCO2) are considered to be green solvents with tunable properties. They have been shown to be ideal media for the synthesis of a variety of metal–organic frameworks (MOFs) with desirable structures and properties (see figure). This review describes advances in MOF synthesis in ILs, scCO2, and IL/scCO2 systems.

[Focus Review]
Bingxing Zhang, Jianling Zhang, Buxing Han
Chem. Asian J., May 24, 2016, DOI: 10.1002/asia.201600323. Read article

Metal–Metalloporphyrin Framework Modified with Flexible tert-Butyl Groups for Selective Gas Adsorption

Metal–Metalloporphyrin Framework Modified with Flexible tert‐Butyl Groups for Selective Gas Adsorption

Alkyl groups as gatekeepers: A porous metal metalloporphyrin–organic framework has been constructed based on a custom-designed porphyrin ligand featuring pendant tert-butyl groups. This material demonstrates interesting selective gas adsorption behavior.

[Communication]
Weijie Zhang, Lukasz Wojtas, Briana Aguila, Pingping Jiang, Shengqian Ma
ChemPlusChem, May 17, 2016, DOI: 10.1002/cplu.201600158. Read article

Metal-Derived Mesoporous Structure of a Carbon Nanofiber Electrocatalyst for Improved Oxygen Evolution Reaction in Alkaline Water Electrolysis

Metal‐Derived Mesoporous Structure of a Carbon Nanofiber Electrocatalyst for Improved Oxygen Evolution Reaction in Alkaline Water Electrolysis

Cheaper catalysts: The lowest overpotential value of the oxygen evolution reaction with cost-effective carbon nanofiber (CNF) electrocatalysts is reported. This can be attributed to the homogeneous placement of active species in the metal-derived mesoporous structure.

[Article]
Xianghua An, Dongyoon Shin, Jaehoon Jeong, Jaeyoung Lee
ChemElectroChem, May 02, 2016, DOI: 10.1002/celc.201600072. Read article

Anionic Metal–Organic Framework for Selective Dye Removal and CO2 Fixation

Anionic Metal–Organic Framework for Selective Dye Removal and CO2 Fixation

A microporous Zn-based anionic metal–organic framework (MOF) is synthesized with triangular 4,4',4″-(pyridine-2,4,6-triyl)tribenzoic acid; it features open channels and proves to be a good capturing agent for cationic dyes. In addition, the Zn-MOF demonstrates excellent catalytic activity for CO2 fixation by cycloaddition reaction with epoxides.

[Communication]
Sanjay Kumar, Gaurav Verma, Wen-Yang Gao, Zheng Niu, Lukasz Wojtas, Shengqian Ma
Eur. J. Inorg. Chem., April 27, 2016, DOI: 10.1002/ejic.201600218. Read article.

A Threefold Interpenetrated Pillared-Layer Metal–Organic Framework for Selective Separation of C2H2/CH4 and CO2/CH4

A Threefold Interpenetrated Pillared‐Layer Metal–Organic Framework for Selective Separation of C2H2/CH4 and CO2/CH4

Trapped wind: A new threefold interpenetrated pillared-layer microporous metal–organic framework, [Zn2(cca)2(4-bpdb)]n(DMF)2n (UTSA-85) (H2cca= 4-carboxycinnamic acid, 4-bpdb=1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene, and DMF=N,N-dimethylformamide), is described. The desolvated framework, UTSA-85 a, exhibits high selectivity for C2H2/CH4 separation as a result of the microporous structure and functional azine-groups decorating the pore channels (see figure).

[Full Paper]
Osamah Alduhaish, Hailong Wang, Bin Li, Hadi D. Arman, Vladimir Nesterov, Khalid Alfooty, Banglin Chen
ChemPlusChem, April 27, 2016, DOI: 10.1002/cplu.201600088. Read article

Fe3O4@MIL-101 – A Selective and Regenerable Adsorbent for the Removal of As Species from Water

Fe3O4@MIL-101 – A Selective and Regenerable Adsorbent for the Removal of As Species from Water

MIL-101(Cr) serves as a host for the in situ synthesis of Fe3O4 nanoparticles. The resulting material shows excellent affinity towards AsIII and AsV species in water. Ca2+, Mg2+, and phosphate ions as well as natural organic matter do not affect the removal efficiency or selectivity. The structural integrity of the host is maintained during the adsorption and desorption process.

[Full Paper]
Karel Folens, Karen Leus, Nina Ricci Nicomel, Maria Meledina, Stuart Turner, Gustaaf Van Tendeloo, Gijs Du Laing, Pascal Van Der Voort
Eur. J. Inorg. Chem., April 21, 2016, DOI: 10.1002/ejic.201600160. Read article.

Carboxylate–Hydrazone Mixed-Linker Metal–Organic Frameworks: Synthesis, Structure, and Selective Gas Adsorption

Carboxylate–Hydrazone Mixed-Linker Metal–Organic Frameworks: Synthesis, Structure, and Selective Gas Adsorption

Two metal–organic frameworks incorporating carboxylate and acylhydrazone moieties are constructed from 4-pyridinecarbaldehyde isonicotinoyl hydrazone (PCIH) and linear dicarboxylate [dcx = 1,4-benzene- (BDC) or 4,4'-biphenyldicarboxylate (BPDC)]. Interpenetrated pillar-layered [Zn2(dcx)2(PCIH)2] frameworks selectively adsorb CO2 over N2.

[Full Paper]
Kornel Roztocki, Irena Senkovska, Stefan Kaskel, Dariusz Matoga
Eur. J. Inorg. Chem., April 21, 2016, DOI: 10.1002/ejic.201600134. Read article.

A Promising White-Light-Emitting Material Constructed from Encapsulating Eu3+/Tb3+ Hybrid Ions into a Robust Microporous Metal–Organic Framework

A Promising White-Light-Emitting Material Constructed from Encapsulating Eu3+/Tb3+ Hybrid Ions into a Robust Microporous Metal–Organic Framework

A fascinating {[Zn(H2thca)0.5(tib)]·5H2O}n [H6thca = p-terphenyl-3,3',3″,5,5',5″-hexacarboxylic acid; tib = 1,3,5-tris(imidazolyl)benzene] metal–organic framework with a permanently porous structure and containing uncoordinated carboxyl groups within the pores is obtained. It emits blue light and can serve as a host for several guest Ln3+ cations; thus, it can exhibit broadband white emission by simple postmodification methods.

[Full Paper]
Xuechuan Gao, Siyuan Chang, Houting Liu, Zhiliang Liu
Eur. J. Inorg. Chem., April 21, 2016, DOI: 10.1002/ejic.201501431. Read article.

Synthesis, Characterization, and Luminescence Modulation of a Metal–Organic Framework Based on a Cyclotriphosphazene-Functionalized Multicarboxylate Ligand

Synthesis, Characterization, and Luminescence Modulation of a Metal–Organic Framework Based on a Cyclotriphosphazene‐Functionalized Multicarboxylate Ligand

Pack it in! An anionic three-dimensional metal–organic framework based on a novel cyclotriphosphazene-functionalized multicarboxylate exhibits luminescence response to different metal ions (see figure).

[Full Paper]
Yajing Ling, Huiming Liu, Jingjing Jiao, Yunlong Feng, Yabing He
ChemPlusChem, April 21, 2016, DOI: 10.1002/cplu.201600129. Read article

High Catalytic Performance of MIL-101-Immobilized NiRu Alloy Nanoparticles towards the Hydrolytic Dehydrogenation of Ammonia Borane

High Catalytic Performance of MIL-101-Immobilized NiRu Alloy Nanoparticles towards the Hydrolytic Dehydrogenation of Ammonia Borane

Ultrafine NiRu alloy nanoparticles are successfully immobilized in the pores of MIL-101 by the double-solvent method combined with the overwhelming reduction approach. The immobilized nanoparticles show high catalytic performance towards the hydrolytic dehydrogenation of ammonia borane.

[Communication]
Sandipan Roy, Pradip Pachfule, Qiang Xu
Eur. J. Inorg. Chem., April 19, 2016, DOI: 10.1002/ejic.201600180. Read article.

Liquid-Phase Epitaxially Grown Metal–Organic Framework Thin Films for Efficient Tandem Catalysis Through Site-Isolation of Catalytic Centers

Liquid‐Phase Epitaxially Grown Metal–Organic Framework Thin Films for Efficient Tandem Catalysis Through Site‐Isolation of Catalytic Centers

Tandem catalysis: A tandem epoxidation/CO2 insertion is shown in a metal–organic framework, composed of two Mn-porphyrin units, which catalyze the epoxidation of an olefin substrate, and a Zn-porphyrin, which catalyzes the epoxide-opening reaction (see figure). A film of this MOF constructed in layer-by-layer fashion is more catalytically active than the bulk prepared crystalline MOF.

[Communication]
M. Hassan Beyzavi, Nicolaas A. Vermeulen, Kainan Zhang, Monica So, Chung-Wei Kung, Joseph T. Hupp, Omar K. Farha
ChemPlusChem, April 13, 2016, DOI: 10.1002/cplu.201600046. Read article

A Rhenium-Functionalized Metal–Organic Framework as a Single-Site Catalyst for Photochemical Reduction of Carbon Dioxide

A Rhenium-Functionalized Metal–Organic Framework as a Single-Site Catalyst for Photochemical Reduction of Carbon Dioxide

A (bpy)Re(CO)3Cl-containing metal–organic framework (MOF) acts as an effective single-site catalyst to photochemically reduce carbon dioxide to carbon monoxide and formate. Mechanistic insights into the monomolecular pathway of the photocatalytic CO2 reduction have been obtained without interference from bimolecular pathways, thanks to site-isolation of the catalytic centers in MOFs.

[Communication]
Ruiyun Huang, Yu Peng, Cheng Wang, Zhan Shi, Wenbin Lin
Eur. J. Inorg. Chem., April 5, 2016, DOI: 10.1002/ejic.201600064. Read article.

Two Six-Connected MOFs with Distinct Architecture: Synthesis, Structure, Adsorption, and Magnetic Properties

Two Six‐Connected MOFs with Distinct Architecture: Synthesis, Structure, Adsorption, and Magnetic Properties

Well connected: Two unusual six-connected metal–organic frameworks were constructed by assembling CoII ions, 5-(4-pyridyl)tetrazole and formate ions. With slight modulation of the coordination environment of the trinuclear cobalt cluster, the two complexes take on completely distinct structures (see figure). One of the complexes strongly interacts with CO2 and might potentially serve as an adsorption material.

[Full Paper]
Guo-Jian Ren, Song-De Han, Yan-Qing Liu, Tong-Liang Hu, Xian-He Bu
ChemPlusChem, April 01, 2016, DOI: 10.1002/cplu.201600092. Read article

SALE-Ing a MOF-Based “Ship of Theseus.” Sequential Building-Block Replacement for Complete Reformulation of a Pillared-Paddlewheel Metal-Organic Framework

SALE-Ing a MOF-Based “Ship of Theseus.” Sequential Building-Block Replacement for Complete Reformulation of a Pillared-Paddlewheel Metal-Organic Framework

Text for Table of Contents: Interchange of a non-interpenetrating Zn based pillared-paddlewheel MOF into an entirely different Ni-based pillared-paddlewheel MOF has been achieved through the combination of solvent assisted linker exchange and transmetalation.

[Communication]
Yan Xu, Nicolaas A. Vermeulen, Yangyang Liu, Joseph T. Hupp, Omar K. Farha
Eur. J. Inorg. Chem., March 18, 2016, DOI: 10.1002/ejic.201600069. Read article.

A Boiling-Water-Stable, Tunable White-Emitting Metal–Organic Framework from Soft-Imprint Synthesis

A Boiling-Water-Stable, Tunable White-Emitting Metal–Organic Framework from Soft-Imprint Synthesis

White light/white heat: A porous metal–organic framework, inspired by conceptually crosscutting the molecular imprint of polymers and the template of zeolites, emits white light in boiling water. The MOF incorporates an effective hard-and-soft divide, in which the EuIII–carboxylate framework holds up the primary grid, whereas the imbedded soft CuI block, like a template, can be dislodged (e.g., by reacting with H2S) from the surrounding sulfur donors while the host net remains intact.

[Communication]
Jun He, Jian Huang, Yonghe He, Peng Cao, Matthias Zeller, Allen D. Hunter, Zhengtao Xu
Chem. Eur. J., January 8, 2016, DOI: 10.1002/chem.201504941. Read article.

Coated/Sandwiched rGO/CoSx Composites Derived from Metal–Organic Frameworks/GO as Advanced Anode Materials for Lithium-Ion Batteries

Coated/Sandwiched rGO/CoSx Composites Derived from Metal–Organic Frameworks/GO as Advanced Anode Materials for Lithium-Ion Batteries

High-performance anode materials: Composites made of reduced graphene oxide (rGO)-coated or sandwiched CoSx are constructed through facile thermal sulfurization of a metal–organic framework/GO precursor, and used as high-performance anode materials for lithium-ion batteries (see scheme).

[Full Paper]
Dongming Yin, Gang Huang, Feifei Zhang, Yuling Qin, Zhaolin Na, Yaoming Wu, Limin Wang
Chem. Eur. J., January 8, 2016, DOI: 10.1002/chem.201504399. Read article.

Origin of the Ability of α-Fe2O3 Mesopores to Activate C-H Bonds in Methane

Origin of the Ability of α-Fe2O3 Mesopores to Activate C-H Bonds in Methane

Origin of the activation: The inner surface structures of the pore wall in mesoporous α-Fe2O3 are mainly comprised of turbostratic ribbons and K crystal faces. They show excellent catalytic performance for methane activation, during which the C-H bonds are converted into C-O bonds in an O2 atmosphere at 140 °C (see figure).

[Full Paper]
Bing Dong, Zhen Han, Yongbo Zhang, Youyi Yu, Aiguo Kong, Yongkui Shan
Chem. Eur. J., January 7, 2016, DOI: 10.1002/chem.201503183. Read article.

A Highly Energetic N-Rich Metal–Organic Framework as a New High-Energy-Density Material

A Highly Energetic N-Rich Metal–Organic Framework as a New High-Energy-Density Material

High-energy MOF: Metal–organic framework [Cu3(MA)2(N3)3] (MA=melamine) was synthesized hydrothermally as gray crystals (see figure). The structural analysis revealed the existence of unusual multiwalled tubular channels and interwoven single and double helices. Its standard molar enthalpy of formation of 1788.73 kJ mol−1 is the highest among previously reported MOF-based energetic materials, and the calculated detonation properties showed that it can be used as a promising explosive.

[Full Paper]
Huabin Zhang , Mingjian Zhang , Ping Lin , Victor Malgras, Jing Tang , Saad M. Alshehri, Yusuke Yamauchi , Shaowu Du, Jian Zhang
Chem. Eur. J., December 10, 2015, DOI: 10.1002/chem.201503561. Read article.

A Post-Synthetically Modified MOF for Selective and Sensitive Aqueous-Phase Detection of Highly Toxic Cyanide Ions

A Post-Synthetically Modified MOF for Selective and Sensitive Aqueous-Phase Detection of Highly Toxic Cyanide Ions

Going hunting! Selective and sensitive detection of toxic cyanide (CN) by a post-synthetically altered metal–organic framework (MOF) has been achieved (see scheme). The aqueous-phase sensing and very low detection limit, the essential prerequisites for an effective sensory material, has been fulfilled by the MOF. Moreover, the present detection level meets the standard set by the World Health Organization (WHO) for the permissible limit of cyanide concentration in drinking water.

[Communication]
Avishek Karmakar, Naveen Kumar, Partha Samanta, Aamod V. Desai, Sujit K. Ghosh
Chem. Eur. J., December 10, 2015, DOI: 10.1002/chem.201503323. Read article.

Metal–Organic Frameworks Containing Missing-Linker Defects Leading to High Hydroxide-Ion Conductivity

Metal–Organic Frameworks Containing Missing-Linker Defects Leading to High Hydroxide-Ion Conductivity

The missing link: The deliberate introduction of defects on fcu frameworks by KOH/EtOH, leading to missing-linker defects and metal cluster basification, is responsible for a boosting of the ion conductivity and depletion of activation energy.

[Full Paper]
Carmen Montoro, Pilar Ocón, Félix Zamora, Jorge A. R. Navarro
Chem. Eur. J., December 8, 2015, DOI: 10.1002/chem.201503951. Read article.

Direct Assembly of Mesoporous Silica Functionalized with Polypeptides for Efficient Dye Adsorption

Direct Assembly of Mesoporous Silica Functionalized with Polypeptides for Efficient Dye Adsorption

An inside job: A polypeptide-functionalized mesoporous silica template is fabricated from a biodegradable poly(ethylene oxide-b-ε-caprolactone) (PEO-b-PCL) diblock copolymer and a poly(tyrosine) (PTyr) biopolymer as a template. Treatment of the silica system by selective solvent extraction removed the block copolymer, while retaining the polypeptide inside the mesostructured silica matrix (see figure).

[Full Paper]
Yi-Syuan Lu, Bishnu Prasad Bastakoti, Malay Pramanik, Victor Malgras, Yusuke Yamauchi, Shiao-Wei Kuo
Chem. Eur. J., December 2, 2015, DOI: 10.1002/chem.201503679. Read article.

Selective Heterogeneous C-H Activation/Halogenation Reactions Catalyzed by Pd@MOF Nanocomposites

Selective Heterogeneous C-H Activation/Halogenation Reactions Catalyzed by Pd@MOF Nanocomposites

A directed heterogeneous C-H activation/halogenation reaction catalyzed by readily synthesized Pd@MOF nanocatalysts was developed (see scheme). The heterogeneous Pd catalysts used were a novel and environmentally benign Fe-based metal–organic framework (MOF) (Pd@MIL-88B-NH2(Fe)) and the previously developed Pd@MIL-101-NH2(Cr). Very high conversions and selectivities were achieved under very mild reaction conditions and in short reaction times.

[Full Paper]
Vlad Pascanu, Fabian Carson, Marta Vico Solano, Jie Su, Xiaodong Zou, Magnus J. Johansson, Belén Martín-Matute
Chem. Eur. J., October 20, 2015, DOI: 10.1002/chem.201502918. Read article.

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