1. Edition - November 2009
169.- Euro
2009. 562 Pages, Hardcover
ISBN-10: 0-470-77932-2
ISBN-13: 978-0-470-77932-3 - John Wiley & Sons






Sample Chapter

Short description
Cumulene reactions have features that are often characteristic of "click reactions," and Cumulenes in Click Reactions presents a comprehensive list of cumulene systems and their reactions, with an emphasis on their "click-like" nature. Following an introduction to the chemistry of cumulenes, the chapters are structured according to the number of carbon atoms in the system. Written by a well-known expert in the field, Cumulenes in Click Reactions is an essential guide for researchers and advanced students in academia and research working in synthetic organic, inorganic, and bioorganic chemistry.

From the contents
Preface

Acknowledgements


1 General Introduction

References


2 1-Carbon Cumulenes

2.1 Sulfines, R2C SO

2.2 Sulfenes, R2C S(O)O

2.3 Other 1-Carbon Cumulenes


3 2-Carbon Cumulenes

3.1 Carbon Oxides, O C O, :CO

3.2 Carbon Sulfides, S C S, S CO

3.3 Carbon Nitrides

3.4 Center Carbon Phosphorallenes, P C P


4 1,2-Dicarbon Cumulenes

4.1 Ketenes, R2C C O

4.2 Thioketenes, R2C C S

4.3 Ketenimines, R2C C NR

4.4 1-Silaallenes, R2C C Si

4.5 1-Phosphaallenes, R2C C P

4.6 Other Metal Allenes


5 1,3-Dicarbon Cumulenes

5.1 Thiocarbonyl S-ylides, R2C S CH2

5.2 2-Azaallenium Salts, R(Ce)C N+ C(Ce)R

5.3 1-Oxa-3-azoniabutatriene Salts, R2C N+ C O

5.4 1-Thia-3-azabutatriene Salts, R2C N+ C S

5.5 Phosphorus Ylides

References


6 1,2,3-Tricarbon Cumulenes

6.1 Allenes, R2C CR2

6.2 [3] Cumulenes, R2C C C CR2

6.3 [4] Cumulenes, R2C C C C CR2

6.4 [5] Cumulenes, R2C C C C C CR2


7 Noncarbon Cumulenes

7.1 Azides, RN N N

7.2 Triazaallenium Salts, RN N+ NR

7.3 Sulfur Oxides

7.4 Sulfur Nitrides

7.5 Cationic Boron Cumulenes, R2N B NR


Index