|  | |
02-01-2010
EurBest in EurJIC: Sulfonic Acid Analogs of Terephthalic and Trimesic Acid as Linkers in Metal-Organic Frameworks - Synthesis of Thermally Robust MOFs
 Acidity brings stability: Thermal stability of over 400 °C is achieved for metal-organic frameworks, if copper(II) is linked by 1,4-benzenedisulfonate or 1,3,5-benzenetrisulfonate. The respective sulfonic acids with appropriate substitution pattern are prepared in an efficient and scalable two-step protocol from bromobenzene derivatives.
Andrea Mietrach, Thomas W. T. Muesmann, Jens Christoffers, Mathias S. Wickleder
DOI: 10.1002/ejic.200900914
|
| |
|
|
|
A Journal of
