Kurzbeschreibung Mit dem dreibändigen Handbook of Metathesis legt Herausgeber Robert H. Grubbs vom California Institute of Technology ein umfassendes und klar gegliedertes Standardwerk zum Thema vor. Grubbs ist einer der Pioniere des Fachgebiets, Die über 40 Beiträge sind ein Muss für jeden, der sich mit organischer Chemie beschäftigt.
Aus dem Inhalt Preface CATALYST DEVELOPMENTS Introduction The Role of the "Tebbe Complex" in Olefin Metathesis The Discovery and Development of High Oxidation State Mo and W Imido Alkylidene Complexes for Alkene Metathesis From ill-defined to well-defined W alkylidene complexes Discovery of Well-defined Ruthenium Olefin Metathesis Catalysts Synthesis of Ruthenium Carbene Complexes Synthesis of Rhodium and Ruthenium Carbene Complexes with a 16-Electron Count Mechanism of Ruthenium-Catalyzed Olefin Metathesis Reactions Intrinsic Reactivity of Ruthenium Carbenes The Discovery and Development of High Oxidation State Alkylidyne Complexes for Alkyne Metathesis Well-defined Metallocarbenes and Metallocarbynes Supported on Oxide Support prepared via Surface Organometallic Chemistry APPLICATIONS IN ORGANIC SYNTHESIS Introduction General Ring-Closing Metathesis Catalytic Asymmetric Olefin Metathesis Tandem RCM Ene-Yne Metathesis Ring Opening Cross Metathesis Ring Expansion Metathesis Reactions Olefin Cross-Metathesis The Olefin Metathesis Reaction in Complex Molecule Construction Applications of Ring Closing Metathesis to Alkaloid Synthesis Radicicol and the Epothilones: Total Synthesis of Novel Anti Cancer Agents Using Ring Closing Metathesis The Use of Olefin Metathesis in Combinatorial Chemistry: Supported and Chromatography-Free Syntheses Metal-Catalyzed Olefin Metathesis in Metal Coordination Spheres Alkyne Metathesis Metathesis of silicon-containing olefins Commercial Applications of Ruthenium Metathesis Processes POLYMER SYNTHESIS Introduction Living Ring-Opening Olefin Metathesis Polymerization Synthesis of Copolymers Conjugated polymers Stereochemistry of ROMP Syntheses and Applications of Bioactive Polymers Generated by the Ring-Opening Metathesis Polymerization (ROMP) Metathesis Polymerization: A Versatile Tool for the Synthesis of Surface-Functionalized Supports and Monolithic Materials Telechelic Polymers from Olefin Metathesis Methodologies ADMET Polymerization Acyclic Diyne Metathesis Utilizing in Situ Transition Metal Catalysts: An Efficient Access to Alkyne-Bridged Polymers Polymerization of Substituted Acetylenes Commercial Applications
