Kurzbeschreibung The whole range of the functionalization of CH-bonds presented for the first time in two volumes. The focus throughout is on topicality and practicability, with reliable and typical experimental procedures included.
Aus dem Inhalt INTRODUCTION AND BACKGROUND CH ACTIVATION AT SP-HYBRIDIZED CARBON ATOMS At terminal alkynes - base-induced or catalyzed addition of terminal alkynes to elektrophiles - Sonogashira coupling reaction - Glaser coupling reaction At HCN - hydrocyanation of alkenes and alkynes - enantioselective addition of HCN to carbonyl compounds CH ACTIVATION AT SP2-HYBRIDIZED CARBON ATOMS At arenes - CO-bond formation by oxidation - by stoichiometric oxidants - by enzymes - supported by artificial transition metal catalysts - towards industrial application: addition to unfunctionalized olefines - Rh-catalyzed carbonylation - Rh-catalyzed and Pt-catalyzed silylation - ortho-selective alkylation of arenes - DOM reaction - intermolecular Pd-catalyzed arylations - Pd-catalyzed arylations via palladacycles - oxidative vinylation: Pd-catalyzed in comparison to Rh-catalyzed processes At alkenes - via cyclometallated Ru-complexes (or: Ru-catalyzed activation of alkenyl esters) - via cyclometallated Rh-complexes - Heck reaction - via cyclopalladation - Wacker oxidation At aldehydes - via cyclopalladation - via cyclometallation with rhodium catalysts - inter- and intramolecular (enantioselective) hydroacylation CH ACTIVATION AT SP3-HYBRIDIZED CARBON ATOMS At functionalized alkanes - in allylic and benzylic position - via palladacycles - via cyclometallated complexes - in a-position of nitriles - asymmetric aldol reactions and related reactions - oxidative free-radical Cyclizations with b-dicarbonyl compounds - aerobic oxidation of alcohols At unfunctionalized alkanes - CO-bond formation by oxidation - radicalic halogenation - photochemical processes - heterogenic catalysis by silica supported hydrido tantalum - Pd-catalyzed carboxylation - olefines by transition metal catalyzed dehydrogenation
