Aqueous Pretreatment of Plant Biomass for Biological and Chemical Conversion to Fuels and Chemicals
Wiley Series in Renewable Resources
1. Auflage Mai 2013
566 Seiten, Hardcover
Wiley & Sons Ltd
Kurzbeschreibung
This book covers the pretreatment of cellulosic biomass to allow sugar release for biological production of fuels and chemicals. Introductory chapters provide the rationale for converting biomass and its importance to national security, balance of trade, and the environment. This is followed by in-depth information on the chemistry and biology of biomass, and biological and chemical conversion routes to release sugars. The book offers an authoritative source on the pretreatment of cellulosic biomass, giving practitioners the most current information. It will also be invaluable to those entering this growing field.
Plant biomass is attracting increasing attention as a sustainable resource for large-scale production of renewable fuels and chemicals. However, in order to successfully compete with petroleum, it is vital that biomass conversion processes are designed to minimize costs and maximize yields. Advances in pretreatment technology are critical in order to develop high-yielding, cost-competitive routes to renewable fuels and chemicals.
Aqueous Pretreatment of Plant Biomass for Biological and Chemical Conversion to Fuels and Chemicals presents a comprehensive overview of the currently available aqueous pretreatment technologies for cellulosic biomass, highlighting the fundamental chemistry and biology of each method, key attributes and limitations, and opportunities for future advances.
Topics covered include:
* The importance of biomass conversion to fuels
* The role of pretreatment in biological and chemical conversion of biomass
* Composition and structure of biomass, and recalcitrance to conversion
* Fundamentals of biomass pretreatment at low, neutral and high pH
* Ionic liquid and organosolv pretreatments to fractionate biomass
* Comparative data for application of leading pretreatments and effect of enzyme formulations
* Physical and chemical features of pretreated biomass
* Economics of pretreatment for biological processing
* Methods of analysis and enzymatic conversion of biomass streams
* Experimental pretreatment systems from multiwell plates to pilot plant operations
This comprehensive reference book provides an authoritative source of information on the pretreatment of cellulosic biomass to aid those experienced in the field to access the most current information on the topic. It will also be invaluable to those entering the growing field of biomass conversion.
Foreword xxi
Series Preface xxiii
Preface xxv
Acknowledgements xxvii
1 Introduction 1
Charles E. Wyman
2 Cellulosic Biofuels: Importance, Recalcitrance, and Pretreatment 17
Lee Lynd and Mark Laser
3 Plant Cell Walls: Basics of Structure, Chemistry, Accessibility and the Influence on Conversion 23
Brian H. Davison, Jerry Parks, Mark F. Davis and Bryon S. Donohoe
4 Biological Conversion of Plants to Fuels and Chemicals and the Effects of Inhibitors 39
Eduardo Ximenes, Youngmi Kim and Michael Ladisch
5 Catalytic Strategies for Converting Lignocellulosic Carbohydrates to Fuels and Chemicals 61
Jesse Q. Bond, David Martin Alonso and James A. Dumesic
6 Fundamentals of Biomass Pretreatment at Low pH 105
Heather L. Trajano and Charles E. Wyman
7 Fundamentals of Aqueous Pretreatment of Biomass 133
Nathan S. Mosier
8 Fundamentals of Biomass Pretreatment at High pH 149
Rocyo Sierra, Mark Holtzapple and Natalia Piamonte
9 Primer on Ammonia Fiber Expansion Pretreatment 173
S.P.S. Chundawat, B. Bals, T. Campbell, L. Sousa, D. Gao, M. Jin, P. Eranki, R. Garlock, F. Teymouri, V. Balan and B.E. Dale
10 Fundamentals of Biomass Pretreatment by Fractionation 205
Poulomi Sannigrahi and Arthur J. Ragauskas
11 Ionic Liquid Pretreatment: Mechanism, Performance, and Challenges 229
Seema Singh and Blake A. Simmons
12 Comparative Performance of Leading Pretreatment Technologies for Biological Conversion of Corn Stover, PoplarWood, and Switchgrass to Sugars 245
Charles E. Wyman, Bruce E. Dale, Venkatesh Balan, Richard T. Elander, Mark T. Holtzapple, Rocyo Sierra Ramirez, Michael R. Ladisch, Nathan Mosier, Y.Y. Lee, Rajesh Gupta, Steven R. Thomas, Bonnie Hames, Ryan Warner and Rajeev Kumar
13 Effects of Enzyme Formulation and Loadings on Conversion of Biomass Pretreated by Leading Technologies 267
Rajesh Gupta and Y.Y. Lee
14 Physical and Chemical Features of Pretreated Biomass that Influence Macro-/Micro-accessibility and Biological Processing 287
Rajeev Kumar and Charles E. Wyman
15 Economics of Pretreatment for Biological Processing 317
Ling Tao, Andy Aden and Richard T. Elander
16 Progress in the Summative Analysis of Biomass Feedstocks for Biofuels Production 341
F.A. Agblevor and J. Pereira
17 High-throughput NIR Analysis of Biomass Pretreatment Streams 361
Bonnie R. Hames
18 Plant Biomass Characterization: Application of Solution- and Solid-state NMR Spectroscopy 375
Yunqiao Pu, Bassem Hallac and Arthur J. Ragauskas
19 Xylooligosaccharides Production, Quantification, and Characterization in Context of Lignocellulosic Biomass Pretreatment 397
Qing Qing, Hongjia Li, Rajeev Kumar and Charles E. Wyman
20 Experimental Pretreatment Systems from Laboratory to Pilot Scale 423
Richard T. Elander
21 Experimental Enzymatic Hydrolysis Systems 457
Todd Lloyd and Chaogang Liu
22 High-throughput Pretreatment and Hydrolysis Systems for Screening Biomass Species in Aqueous Pretreatment of Plant Biomass 477
Jaclyn DeMartini and Charles E. Wyman
23 Laboratory Pretreatment Systems to Understand Biomass Deconstruction 495
Bin Yang and Melvin Tucker
Acknowledgments 520
References 520
Index
