Inorganic Structural Chemistry

Preface.

1 Introduction.

2 Description of Chemical Structures.

3 Symmetry.

4 Polymorphism and Phase Transitions.

5 Chemical Bonding and Lattice Energy.

6 The Effective Size of Atoms.

7 Ionic Compounds.

8 Molecular Structures I: Compounds of Main Group Elements.

9 Molecular Structures II: Compounds of Transition Metals.

10 Molecular Orbital Theory and Chemical Bonding in Solids.

11 The Element Structures of the Nonmetals.

12 Diamond-like Structures.

13 Polyanionic and Polycationic Compounds. Zintl Phases.

14 Packings of Spheres. Metal Structures.

15 The Sphere-packing Principle for Compounds.

16 Linked Polyhedra.

17 Packings of Spheres with Occupied Interstices.

18 Symmetry as the Organizing Principle for Crystal Structures.

19 Physical Properties of Solids.

20 Nanostructures.

21 Pitfalls and Linguistic Aberrations.

References.

Answers to the Problems.

Index.

"I found this book useful and I would use it in courses of chemistry or physics of the solid state, advanced inorganic chemistry for undergraduate and postgraduate students." (The Higher Education Academy Physical Sciences Centre, June 2008)

"...quite useful for...advanced undergraduate and graduate chemistry students." (CHOICE, July 2007)

" ... very useful reading for graduate student coursework ... recommend the work ... with its compact yet broad coverage review of the subject." (Applied Organometallic Chemistry, December 2006)

Ulrich Müller. Born in 1940 in Bogotá, Colombia. School attendance in Bogotá, then in Elizabeth, New Jersey, and finally in Fellbach, Germany. Studied chemistry at the Technische Hochschule in Stuttgart, Germany, obtaining the degree of Diplom-Chemiker in 1963. Work on the doctoral thesis in inorganic chemistry was performed in Stuttgart and at Purdue University in West Lafayette, Indiana, in the research groups of K. Dehnicke and K. S. Vorres, respectively. The doctor's degree in natural sciences (Dr. rer. nat.) was awarded by the Technische Hochschule Stuttgart in 1966. Subsequent post-doctoral work in crystallography and crystal structure determinations was performed in the research group of H. Bärnighausen at the Universit ¨at Karlsruhe, Germany. Appointed in 1972 as professor of inorganic chemistry at the Philipps-Universität Marburg, Germany, then from 1992 to 1999 at the Universit¨at Kassel, Germany, and since 1999 again in Marburg. Helped installing a graduate school of chemistry as visiting professor at the Universidad de Costa Rica from 1975 to 1977. Courses in spectroscopic methods were repeatedly given at different universities in Costa Rica, Brazil and Chile. Main areas of scientific interest: synthetic inorganic chemistry, crystallography and crystal structure systematics, crystallographic group theory. Co-author of Chemie, a textbook for beginners, Schwingungsspektroskopie, a textbook about the application of vibrational spectroscopy, and of Schwingungsfrequenzen I and II (tables of characteristic molecular vibrational frequencies); co-author and co-editor of International Tables for Crystallography, Vol. A1.

U. Müller, Philipps-Universitat Marburg, Germany