Colloid Science
Principles, Methods and Applications
2. Auflage März 2010
398 Seiten, Hardcover
Wiley & Sons Ltd
Kurzbeschreibung
Important across a variety of industries, colloidal systems form the basis of a wide range of products - cosmetics, toiletries, processed foodstuffs, and photographic film. A detailed understanding of their formation, control and application is required, yet many new graduate or postgraduate chemists or chemical engineers have little direct experience with colloidal systems. Based on lectures given at Bristol Colloid Centre Spring School, Colloid Science: Principles, Methods and Applications, 2nd Edition provides a thorough introduction. Two new chapters on emulsions and interparticle forces add to an understanding of colloidal systems.
Colloidal systems are important across a range of industries, such as the food, pharmaceutical, agrochemical, cosmetics, polymer, paint and oil industries, and form the basis of a wide range of products (eg cosmetics & toiletries, processed foodstuffs and photographic film). A detailed understanding of their formation, control and application is required in those industries, yet many new graduate or postgraduate chemists or chemical engineers have little or no direct experience of colloids.
Based on lectures given at the highly successful Bristol Colloid Centre Spring School, Colloid Science: Principles, Methods and Applications provides a thorough introduction to colloid science for industrial chemists, technologists and engineers. Lectures are collated and presented in a coherent and logical text on practical colloid science.
Introduction
Acknowledgements
List of Contributors
1 Introduction to Colloids
Roy Hughes
1.1 Introduction
1.2 Basic Definitions
1.3 Stability
1.4 The end of colloids
References
2 Charge in Colloidal Systems
David Fermin and Jason Riley
2.1 Introduction
2.2 The Origin of Surface Charge
2.3 The Electrochemical Double layer
2.4 Electrokinetic Properties
References
3 Stability of charge stabilised colloids
John Eastman
3.1 Introduction
3.2 The colloidal pair potential
3.3 Criteria for stability
3.4 Kinetics of coagulation
3.5 Conclusions
References
4 Surfactant aggregation and adsorption at interfaces
Julian Eastoe
4.1 Characteristic features of surfactants
4.2 Classification and applications of surfactants
4.3 Adsorption of surfactants at interfaces
4.4 Surfactant solubility
4.5 Micellisation
4.6 Liquid Crystalline mesophases
4.7 Advanced Surfactants
References
5 Microemulsions
Julian Eastoe
5.1 Microemulsions: Definition and History
5.2 Theory of Formation and Stability
5.3 Physicochemical Properties
5.4 Developments and Applications
References
6 Emulsions
Brian Vincent
6.1 Introduction
6.2 Preparation
6.3 Stability
References
Textbooks and General reading
7 Polymers and Polymer Solutions
Terence Cosgrove
7.1 Introduction
7.2 Polymerisation
7.3 Copolymers
7.4 Polymer physical properties
7.5 Polymer Uses
7.6 Theoretical Models of Polymer Structure
7.7 Measuring Polymer Molecular Weight
7.8 Polymer Solutions
References
8 Polymers at Interfaces
Terence Cosgrove
8.1 Introduction
8.2 Adsorption of polymers
8.3 Models and Simulations for Terminally Attached Chains
8.4 Experimental Aspects
8.5 Copolymers
8.6 Polymer brushes
8.7 Conclusions
References
9 Effect of Polymers on Colloid Stability
Jeoren van Duijneveldt
9.1 Introduction
9.2 Particle interaction potential
9.3 Steric Stabilisation
9.4 Depletion interactions
9.5 Bridging Interactions
9.6 Conclusion
References
10 Wetting of Surfaces
Paul Reynolds
10.1 Introduction
10.2 Surfaces and Definitions
10.3 Surface Tension
10.4 Surface Energy
10.5 Contact Angles
10.6 Wetting
10.7 Liquid Spreading and Spreading Coefficients
10.8 Cohesion and Adhesion
10.9 Two liquids on a surface
10.10 Detergency
10.11 Spreading of a Liquid on a Liquid
10.12 Characterisation of a Solid Surface
10.13 Polar and Dispersive components
10.14 Polar Materials
10.15 Wettability Envelopes
10.16 Measurement Methods
10.17 Conclusions
References
11 Aerosols
Nana-Owusua A. Kwamena and Jonathan P. Reid
11.1 Introduction
11.2 Generating and Sampling Aerosol
11.3 Determining the particle Concentration and Size
11.4 Determining Particle Composition
11.5 The Equilibrium State of Aerosols
11.6 The Kinetics of Aerosol Transformation
11.7 Concluding Remarks
References
12 Practical Rheology
Roy Hughes
12.1 Introduction
12.2 Making Measurements
12.3 Rheometry & Viscoelasticity
12.4 Examples of Soft Materials
12.5 Summary
References
13 Scattering and Reflection Techniques
Robert Richardson
13.1 Introduction
13.2 The Principle of a Scattering Experiment
13.3 Radiation for Scattering Experiments
13.4 Light Scattering
13.5 Dynamic Light Scattering
13.6 Small Angle Scattering
13.7 Sources of Radiation
13.8 Small Angle Scattering Apparatus
13.9 Scattering and absorption by Atoms
13.10 Scattering Length Density
13.11 Small Angle Scattering from a Dispersion
13.12 Form Factor for Spherical Particle
13.13 Determining particle size from SANS and SAXS
13.14 Guinier plots to determine radius of gyration
13.15 Determination of particle shape
13.16 Polydispersity
13.17 Determination of particle size distribution
13.18 Alignment of anisotropic particles
13.19 Concentrated Dispersions
13.20 Contrast Variation using SANS
13.21 High Q Limit: Porod Law
13.22 Introduction to X-Ray and Neutron Reflection
13.23 Reflection Experiment
13.24 A Simple Example of a Reflection Measurement
13.25 Conclusion
References
14 Optical Manipulation
Paul Bartlett
14.1 Introduction
14.2 Manipulating matter with light
14.3 Force generation in optical tweezers
14.4 Nanofabrication
14.5 Single particle dynamics
14.6 Conclusions
References
15 Electron Microscopy
Sean Davis
15.1 General Features of (Electron) Optical Imaging Systems
15.2 Conventional TEM
15.3 Conventional SEM
15.4 Summary
References
16 Surface Forces
Wuge Briscoe
16.1 Introduction
16.2 Forces and energy; size and shape
16.3 Surface force measurement techniques
16.4 Different types of surface forces
16.5 Recent examples of surface force measurement
16.6 Future challenges
References
Index
