Next-Generation Electrochromic Devices
From Multifunctional Materials to Smart Glasses
1. Edition July 2025
368 Pages, Hardcover
5 Pictures (5 Colored Figures)
Monograph
Short Description
Covers the basic concepts of multifunctional materials and their potential exploitation for the design of electrochromic and integrated systems.
Comprehensive reference focusing on features of promising new materials and devices for electrochromic and integrated multifunctional systems
Next-Generation Electrochromic Devices: From Multifunctional Materials to Smart Glasses covers the basic concepts and the potential use of electrolytes, conducting polymers and multifunctional materials for the development of electrochromic (EC) and integrated systems, focusing on the influence of solid-state electrolytes and interface features on the design of new device structures and simplified manufacturing.
The book is divided into three parts. Part I explores the chemistry of the main components of devices with a special focus on the main critical material issues, covering mixed-ion and electron conductors, electrodes, and more. Part II describes EC and multifunctional devices, such as photoelectrochromic smart windows and see-through ECOLED displays, and the main characterization techniques for the study of material properties, interfaces and device performance. Part III comprehends device manufacturing, scale-up procedures, and discusses the main benefits of smart windows in terms of energy savings, visual comfort, and environmental impact, proposing contextually a multitude of pioneering ideas and concepts with a specific insight into emerging devices in the era of Artificial Intelligence (AI), immersive reality and invisible technologies.
Next-Generation Electrochromic Devices includes information on:
* Inorganic and organic electrochromic materials, including graphene, 3D transitional metal oxides, Prussian blue, viologens, conducting polymers, organic mixed ionic and electronic materials, and highly transparent electrodes
* Electrolytes including inorganic, liquid, gel, and solid-state polymers, their ionic conductivity and transport properties
* Thin film deposition methods: chemical deposition through solution processing techniques, sol-gel, Langmuir-Blodgett, electrochemical and physical deposition by means thermal and electron-beam evaporation, sputtering, pulsed laser, and molecular beam epitaxy deposition
* Electrochemical analysis of materials, interface, and device durability
* Organic mixed ionic and electronic conductor materials for innovative and multifunctional optoelectronic systems
* Optical, structural, chemical, and physical methods for the study of electrochromism and material properties including NMR, X-Ray diffraction analysis, XPS, UV-Vis, FTIR, and Raman spectroscopy
* Energy efficiency of EC glazings and their impact on thermal and visual comfort
* Emerging materials for chromogenic systems, smart windows, and new energy devices
* Fully integrated ECOLED see-through displays and multifunctional smart devices for immersive reality and invisible technologies
* Impact of AI and next-generation technologies on social, human, and environmental changes
Next-Generation Electrochromic Devices is an essential reference on the subject for materials scientists, chemists, physicists, as well as architects, electrical and civil engineers. It can be also a source of inspiration for artists, graphic designers, and art workers.
Preface
About the Author
Acknowledgments
1. Introduction
1.1. Electrochromism and Electrochemistry: a Brief Note on the History and Recent Evolution
Part I: Materials
2. Electrochromic Materials
2.1. Inorganic Electrochromic Materials
2.2. Two Dimensional (2D) Electrochromic Materials
2.3 Organic Electrochromic Materials
3 Mixed Ion and Electron Conductors (MIECs)
3.1 Semiconducting Polymers and Small Molecules
3.2 Structure-Properties Relationship and Charge Transport in Disordered Organic Materials
3.3 Potential Impact of Mixed Conductors on the Design of new EC and Multifunctional Devices
4. Electrolytes
4.1 Liquid Electrolytes
4.2 Polymer Electrolytes: from Gel to Solid Polymers
4.3 Inorganic Electrolytes
5 Electrodes
5.1 Transparent and Conducting oxides
5.2 Carbon-Based Electrode Materials
5.3 Metal Nanowires and Metal Grids
6 Critical Material Issues
Part II: Devices
7. Device Structure: the Key Role of the Interfaces in the Device Design
7.1 Electrochromic Device
7.2 Electrochromic Multifunctional Devices
8. Thin Films Processing Technologies
8.1 Chemical Deposition
8.2 Physical Deposition
9. Analysis of Device Performance
9.1. Optical Spectroscopy
9.2 Electrochemical Analysis
9.3 Chemical and Physical Methods for Analysis of Electrochromism and Material Properties
9.4 Characterization of Mixed Ion Electronic Conduction Materials
Part III: Industrial Scale-up, Energy and Environment, Next-Generation Technologies
10 Construction of Smart Windows: From Laboratory to Industry Scale-Up
10.1 Manufacturing Processes: Materials and Deposition Techniques
10.2 Scale-up Procedures: EC Windows and Large Area PV modules
10.3 Laminated Smart Windows and Adhesive EC Smart Films
11. Energy-Efficient Glazings for Green Buildings
11.1 Energy Demand and Consumption in Buildings: Energy Saving of EC Glazings
11.2 Effect of Electrochromic Glazings on Visual Comfort: Usable Daylight Illuminance (UDI) and Discomfort Glare Index (DGI)
12 Emerging and Next-Generation Technologies for Dynamic Tintable Windows
12.1 Smart Photoelectrochromic and Thermochromic Windows: Green Technologies Towards More Sustainable Buildings
12.2 Emerging and Next-Generation Technologies
12.3 The New Era of Artificial Inteligence: Towards Immersive Reality and Invisible Technologies
Bibliography