Reactive Distillation Design and Control

1. Edition November 2008
608 Pages, Hardcover
Monograph
Short Description
Reactive distillation is an economical and environmentally friendly procedure that combines distillation and chemical reaction into a single step. To address the increasing importance of reactive distillation in the petroleum and chemical industries, this book deals with the design of reactive distillation columns and their control systems in an integrated manner.
Reactive distillation has economical and environmental advantages
Reactive distillation is a breakthrough process innovation with numerous applicationsin the petroleum and chemical industries. In systems with the appropriate chemistryand vapor-liquid phase equilibrium, it combines the reaction and separation operations,which reduces energy and capital costs and environmental impact. After an overview of the fundamentals, limitations, and scope of reactive distillation, Reactive Distillation Design and Control:
* Uses rigorous models for steady-state design and dynamic analysis of different types of reactive distillation columns
* Quantitatively compares the economics of reactive distillation columns with conventional multi-unit processes
* Goes beyond traditional steady-state design that considers primarily the capital investment andenergy costs when analyzing the control structure and the dynamic robustness of disturbances
* Discusses how to maximize the economic and environmental benefits of reactive distillation technology
Written by authors who have a background in design and control with an emphasis on practical engineering solutions to real industrial problems, this guide forgoes intricate, complicated mathematics and complex methods of analysis and gets down to business. It's an accessible reference for chemical, process, and petroleum engineers and undergraduate and graduate students in chemical engineering.
PART 1: STEADY-STATE DESIGN OF IDEAL QUATERNARY SYSTEM
Chapter 2: Parameter Effects
Chapter 3: Economic Comparison of Reactive Distillation with a Conventional Process
Chapter 4: Neat Operation versus Using Excess Reactant
PART 2: STEADY-STATE DESIGN OF OTHER IDEAL SYSTEMS
Chapter 5: Ternary Reactive Distillation Systems
Chapter 6: Ternary Decomposition Reaction
PART 3: STEADY-STATE DESIGN OF REAL CHEMICAL SYSTEMS
Chapter 7: Steady-State Design for Acetic Acid Esterification
Chapter 8: Design of TAME Reactive Distillation Systems
Chapter 9: Design of MTBE and ETBE Reactive Distillation Columns
PART 4: CONTROL OF IDEAL SYSTEMS
Chapter 10: Control of Quaternary Reactive Distillation Columns
Chapter 11: Control of Excess-Reactant System
Chapter 12: Control of Ternary Reactive Distillation Columns
PART 5: CONTROL OF REAL SYSTEMS
Chapter 13: Control of MeAc/ EtAc/IPAc/BuAc/AmAc Systems
Chapter 14: Control of TAME Plantwide Process
Chapter 15 Control of MTBE and ETBE Reactive Distillation Columns
PART 6: HYBRID AND NON-CONVENTIONAL SYSTEMS
Chapter 16: Design and Control of Column/Side- Reactor Systems
Chapter 17: Effect of Boiling Point Rankings on the Design of Reactive Distillation
Chapter 18: Effects of Feed Tray Locations on the Design and Control of Reactive Distillation
APPENDIX
A1. Reference
A2. Catalog of Types of Real Reactive Distillation Systems